ethyl 2-phenoxypropenoate

Base Information

• Chemical Name: ethyl 2-phenoxypropenoate
• CAS No.: 16929-31-0
• Molecular Formula: C₁₁H₁₂O₃
• Molecular Weight: 192.214
• Mol file: 16929-31-0.mol

Synonyms:ethyl 2-phenoxypropenoate

Chemical Property of ethyl 2-phenoxypropenoate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of ethyl 2-phenoxypropenoate

There total 2 articles about ethyl 2-phenoxypropenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + ethyl 2-phenoxy-2-diethylphosphonoacetate (86728-37-2) → ethyl 2-phenoxypropenoate (16929-31-0)

Guidance literature:

ethyl 2-phenoxy-2-diethylphosphonoacetate; With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 20 ℃; for 0.166667h;

formaldehyd; In tetrahydrofuran; Reflux;

DOI:10.1002/ejoc.201901877

Reference yield:

2,2-Diphenoxy-propionic acid ethyl ester → ethyl 2-phenoxypropenoate (16929-31-0)

Guidance literature:

With toluene-4-sulfonic acid;

Reference yield: 60.0%

ethyl 2-phenoxypropenoate (16929-31-0) + 2-Methoxybenzoic acid (579-75-9) → (Z)-ethyl 3-(2-methoxyphenyl)-2-phenoxyacrylate

Guidance literature:

With palladium(II) trifluoroacetate; silver carbonate; In 1,4-dioxane; dimethyl sulfoxide; at 130 ℃; for 24h; stereoselective reaction; Sealed tube; Inert atmosphere;

DOI:10.1002/ejoc.201901877

upstream raw materials:

formaldehyd

ethyl 2-phenoxy-2-diethylphosphonoacetate