tetraphenylphosphonium (2,2'-bipyridine-5-sulfonate)

Base Information

• Chemical Name: tetraphenylphosphonium (2,2'-bipyridine-5-sulfonate)
• CAS No.: 127618-89-7
• Molecular Formula: C₁₀H₇N₂O₃S*C₂₄H₂₀P
• Molecular Weight: 574.64
• Mol file: 127618-89-7.mol

Synonyms:tetraphenylphosphonium (2,2'-bipyridine-5-sulfonate)

Chemical Property of tetraphenylphosphonium (2,2'-bipyridine-5-sulfonate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetraphenylphosphonium (2,2'-bipyridine-5-sulfonate)

There total 2 articles about tetraphenylphosphonium (2,2'-bipyridine-5-sulfonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tetraphenylphosphonium bromide (2751-90-8) + 2,2'-bipyridine-5-sulphonic acid (2767-24-0) → tetraphenylphosphonium (2,2'-bipyridine-5-sulfonate) (127618-89-7)

Guidance literature:

With ammonium hydroxide; In water;

Reference yield:

[2,2]bipyridinyl (366-18-7) → tetraphenylphosphonium (2,2'-bipyridine-5-sulfonate) (127618-89-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 25 percent / Oleum (30 Gew_.percent SO₃), H₂SO₄ / 24 h / 220 °C

2: 95 percent / aq. NH₃ / H₂O

With ammonium hydroxide; sulfuric acid; sulfur trioxide; In water;

Reference yield: 99.0%

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) (12146-37-1,124717-04-0) + tetraphenylphosphonium (2,2'-bipyridine-5-sulfonate) (127618-89-7) → tetraphenylphosphonium {(2,2'-bipyridine-5-sulfonate)tetracarbonylmolybdenum(0)} (127619-00-5)

Guidance literature:

In tetrahydrofuran; dichloromethane; byproducts: C7H8; addn. of tetracarbonylnorbornadiene-complex to soln. of 2,2-bipydridine derivative in CH2Cl2/THF, color change from yellow to red, stirred (10 h, room temp., exclusion of light); evapn., dark red residue (if not solid, ground at -196°C), washed (Et2O, twice), soln. (CH2Cl2), layered with Et2O, crystn. (1 w); elem. anal.;

upstream raw materials:

tetraphenylphosphonium bromide

2,2'-bipyridine-5-sulphonic acid

[2,2]bipyridinyl

Downstream raw materials:

tetraphenylphosphonium {(2,2'-bipyridine-5-sulfonate)tetracarbonylmolybdenum⁽⁰⁾}

Tetraphenylphosphonium {(2,2'-bipyridin-5-sulfonat)(1,2-cyclohexandiolato)dioxoosmium(VI)

tetraphenylphosphonium {(2,2'-bipyridine-5-sulfonato)oxodiperoxomolybdenum(VI)} dihydrate

tetraphenylphosphonium {(2,2'-bipyridine-5-sulfonate)tetracarbonylchromium⁽⁰⁾}

Refernces