5,10,15,20-tetrakis(p-cyanophenyl)zincporphyrin

Base Information

• Chemical Name: 5,10,15,20-tetrakis(p-cyanophenyl)zincporphyrin
• CAS No.: 102421-98-7
• Molecular Formula: C₄₈H₂₄N₈Zn
• Molecular Weight: 778.162
• Mol file: 102421-98-7.mol

Synonyms:5,10,15,20-tetrakis(p-cyanophenyl)zincporphyrin

Chemical Property of 5,10,15,20-tetrakis(p-cyanophenyl)zincporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of 5,10,15,20-tetrakis(p-cyanophenyl)zincporphyrin

There total 8 articles about 5,10,15,20-tetrakis(p-cyanophenyl)zincporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

5,10,15,20-tetrakis-(4-[(trimethylsilyl)ethynyl]phenyl)porphyrin-zinc(II) (502612-98-8) + water (7732-18-5) → 5,10,15,20-tetrakis-(4-(ethynyl)phenyl)porphyrinzinc(II) (102421-98-7)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; (N2); Schlenk technique; soln. of Bu4NF in THF was added to soln. of Zn complex in THF; stirred at room temp. for 30 min; quenched with H2O; filtered;

DOI:10.1016/j.jorganchem.2009.02.020

Reference yield: 95.0%

5,10,15,20-tetrakis(4-cyanophenyl)porphirin (14609-51-9) → 5,10,15,20-tetrakis(p-cyanophenyl)zincporphyrin (102421-98-7)

Guidance literature:

With zinc diacetate; In methanol; chloroform; for 5h;

DOI:10.1142/S108842461100435X

Reference yield: 95.0%

4,4',4'',4'''-(porphyrin-5,10,15,20-tetrayl)tetrabenzonitrile + zinc diacetate (557-34-6) → 5,10,15,20-tetrakis-(4-(ethynyl)phenyl)porphyrinzinc(II) (102421-98-7)

Guidance literature:

In methanol; chloroform; ligand refluxed with excess Zn compd. for 5 h; chromd. (SiO2, CHCl3), elem. anal.;

DOI:10.1002/ejic.200801047

upstream raw materials:

zinc diacetate

5,10,15,20-tetrakis-(4-[(trimethylsilyl)ethynyl]phenyl)porphyrin-zinc(II)

water

4-hydroxy-benzaldehyde