C₁₁H₁₆BrP

Base Information

• Chemical Name: C₁₁H₁₆BrP
• CAS No.: 1354744-11-8
• Molecular Formula: C₁₁H₁₆BrP
• Molecular Weight: 259.126
• Mol file: 1354744-11-8.mol

Synonyms:C₁₁H₁₆BrP

Chemical Property of C₁₁H₁₆BrP

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of C₁₁H₁₆BrP

There total 18 articles about C₁₁H₁₆BrP which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(Rp)-(2-bromophenyl)(tert-butyl)(methyl)phosphine-borane (1245628-41-4,1248519-23-4,1355197-78-2) → C11H16BrP (1354744-11-8)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; In tetrahydrofuran; for 1.5h; Inert atmosphere; Reflux;

DOI:10.1021/ol101936w

Reference yield:

(Rp)-(2-bromophenyl)(tert-butyl)(methyl)phosphine-borane (1245628-41-4,1248519-23-4,1355197-78-2) → C11H16BrP (1354744-11-8)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; In tetrahydrofuran; at 70 ℃; for 2h; Inert atmosphere;

Reference yield:

methylmagnesium bromide (75-16-1) + tert-butyldichlorophosphine (25979-07-1) + 2,3-dibromobenzene (583-53-9) → C11H16BrP (1354744-11-8)

Guidance literature:

2,3-dibromobenzene; With TurboGrignard; In tetrahydrofuran; at -20 - -15 ℃; Inert atmosphere;

methylmagnesium bromide; tert-butyldichlorophosphine; In tetrahydrofuran; diethyl ether; at -70 - 20 ℃; Inert atmosphere;

DOI:10.1021/ol101936w

upstream raw materials:

methylmagnesium bromide

tert-butyldichlorophosphine

2,3-dibromobenzene

(Rp)-(2-bromophenyl)(tert-butyl)(methyl)phosphine-borane

Downstream raw materials:

(S,S)-1,2-bis(tert-butylmethylphosphino)benzene