fluoro(methyl)phenylarsine

Base Information

• Chemical Name: fluoro(methyl)phenylarsine
• CAS No.: 151041-80-4
• Molecular Formula: C₇H₈AsF
• Molecular Weight: 186.061
• Mol file: 151041-80-4.mol

Synonyms:fluoro(methyl)phenylarsine

Chemical Property of fluoro(methyl)phenylarsine

Chemical Property:

Purity/Quality:

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Technology Process of fluoro(methyl)phenylarsine

There total 1 articles about fluoro(methyl)phenylarsine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

bromo(methyl)phenylarsine (696-25-3) → fluoro(methyl)phenylarsine (151041-80-4)

Guidance literature:

With silver fluoride; In acetone; for 12h;

DOI:10.1016/0022-328X(93)80397-T

Reference yield: 64.0%

(R*,R*)-(+/-)-(acetonitrile)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate (113587-85-2) + fluoro(methyl)phenylarsine (151041-80-4) → {(R*),(R*,R*)-(+/-)-(η5-cyclopentadienyl)(fluoromethylphenylarsine)(1,2-phenylenebis(methylphenylphosphine))iron(II)} hexafluorophosphate * dichloromethane + {(S*),(R*,R*)-(+/-)-(η5-cyclopentadienyl)(fluoromethylphenylarsine)(1,2-phenylenebis(methylphenylphosphine))iron(II)} hexafluorophosphate * acetone

Guidance literature:

With CH₂Cl₂; acetone; In dichloromethane; boiled for 12 h in darkness; addn. of diethyl ether to the cooled soln., fractional crystn. of the ppt. yields the (R*),(R*,R*)-isomer, mother liquor is evapd. to dryness, residue is dissolved in acetone, addn. of diethyl ether yields the (S*),(R*,R*)-isomer, elem. anal.;

DOI:10.1016/0022-328X(93)80397-T

upstream raw materials:

bromo(methyl)phenylarsine