(R(*),R(*))-(+/-)-(acetonitrile)(η(5)-cyclopentadienyl)[1,2-phenylenebis(methylphenylphosphine)]iron(II) hexafluorophosphate

Base Information

• Chemical Name: (R(*),R(*))-(+/-)-(acetonitrile)(η(5)-cyclopentadienyl)[1,2-phenylenebis(methylphenylphosphine)]iron(II) hexafluorophosphate
• CAS No.: 113587-85-2
• Molecular Formula: C₂₇H₂₈FeNP₂*F₆P
• Molecular Weight: 629.285
• Mol file: 113587-85-2.mol

Synonyms:

Chemical Property of (R(*),R(*))-(+/-)-(acetonitrile)(η(5)-cyclopentadienyl)[1,2-phenylenebis(methylphenylphosphine)]iron(II) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (R(*),R(*))-(+/-)-(acetonitrile)(η(5)-cyclopentadienyl)[1,2-phenylenebis(methylphenylphosphine)]iron(II) hexafluorophosphate

There total 1 articles about (R(*),R(*))-(+/-)-(acetonitrile)(η(5)-cyclopentadienyl)[1,2-phenylenebis(methylphenylphosphine)]iron(II) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

ammonium hexafluorophosphate + dicarbonylcyclopentadienylbromoiron(II) + (R*,R*)-(+/-)-1,2-phenylenebis(methylphenylphosphine) (122331-49-1) → (R*,R*)-(+/-)-(acetonitrile)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate (113587-85-2)

Guidance literature:

In acetonitrile; Irradiation (UV/VIS); under Ar, irradn. with UV lamp, 50 min, redn. of vol., addn. of aq. NH4PF6; addn. of diethyl ether, stirring, 18 h, filtration, washing with diethyl ether, drying; elem. anal.;

Reference yield: 91.0%

(R(*),R(*))-(+/-)-(acetonitrile)(η(5)-cyclopentadienyl)[1,2-phenylenebis(methylphenylphosphine)]iron(II) hexafluorophosphate (113587-85-2,125876-79-1,122331-51-5) + (+/-)-(3-chloropropyl)(phenyl)arsine (142599-71-1) → [(R(*)),(R(*),R(*))/(R(*)),(S(*),S(*))]-[(3-chloropropyl)(phenyl)arsine](η(5)-cyclopentadienyl)[1,2-phenylenebis(methylphenylphosphine)]iron(II) hexafluorophosphate (161814-80-8,142600-38-2,142697-29-8)

Guidance literature:

In ethanol; Ar-atmosphere; refluxing (3 h); crystn. on concg. (-10°C), washing (EtOH / Et2O = 1 : 2, Et2O), drying (vac.); elem. anal.;

Reference yield: 91.0%

(R*,R*)-(+/-)-(acetonitrile)(η5-cyclopentadienyl){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate (113587-85-2) + bromo(methyl)phenylarsine (696-25-3) → {(R*,R*)-(+/-)-(bromomethylphenylarsine)(η5-cyclopentadienyl)(1,2-phenylenebis(methylphenylphosphine))iron(II)} hexafluorophosphate

Guidance literature:

In dichloromethane; boiled for 12 h; addn. of diethyl ether yields a mixture of (R*),(R*,R*)-/(S*),(R*,R*)-diastereomers (ratio 2:1), elem. anal.;

DOI:10.1016/0022-328X(93)80397-T

upstream raw materials:

(R*,R*)-(+/-)-1,2-phenylenebis(methylphenylphosphine)

Downstream raw materials:

{(R*,R*),(S*)}-(+/-)-(η5-cyclopentadienyl)(ethylphenylphosphine){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate

{(R*,R*),(R*)}-(+/-)-(η5-cyclopentadienyl)(ethylphenylphosphine){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate hemidichloromethane solvate

{(R*,R*),(R*)}-(+/-)-(η5-cyclopentadienyl)(methylphenylphosphine){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate hemidichloromethane solvate

{(R*,R*),(S*)}-(+/-)-(η5-cyclopentadienyl)(methylphenylphosphine){1,2-phenylenebis(methylphenylphosphine)}iron(II) hexafluorophosphate monoacetone solvate