(2S,4S,6S)-2-(((2R,6R)-6-((E)-3-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-hydroxybutyl)-2-methoxy-3-oxotetrahydro-2H-pyran-2-yl)-3-methylbut-1-enyl)-4-oxotetrahydro-2H-pyran-2-yl)methyl)-6-((R)-2-(tert-butyldiphenylsilyloxy)-4-(tert-butylthio)-4-oxobutyl)-3,3-dimethyltetrahydro-2H-pyran-4-yl acetate

Base Information

Chemical Name:(2S,4S,6S)-2-(((2R,6R)-6-((E)-3-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-hydroxybutyl)-2-methoxy-3-oxotetrahydro-2H-pyran-2-yl)-3-methylbut-1-enyl)-4-oxotetrahydro-2H-pyran-2-yl)methyl)-6-((R)-2-(tert-butyldiphenylsilyloxy)-4-(tert-butylthio)-4-oxobutyl)-3,3-dimethyltetrahydro-2H-pyran-4-yl acetate
CAS No.:1239579-41-9
Molecular Formula:C₆₂H₈₈O₁₃SSi
Molecular Weight:1101.52
Hs Code.:

(2S,4S,6S)-2-(((2R,6R)-6-((E)-3-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-hydroxybutyl)-2-methoxy-3-oxotetrahydro-2H-pyran-2-yl)-3-methylbut-1-enyl)-4-oxotetrahydro-2H-pyran-2-yl)methyl)-6-((R)-2-(tert-butyldiphenylsilyloxy)-4-(tert-butylthio)-4-oxobutyl)-3,3-dimethyltetrahydro-2H-pyran-4-yl acetate

Synonyms:(2S,4S,6S)-2-(((2R,6R)-6-((E)-3-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-hydroxybutyl)-2-methoxy-3-oxotetrahydro-2H-pyran-2-yl)-3-methylbut-1-enyl)-4-oxotetrahydro-2H-pyran-2-yl)methyl)-6-((R)-2-(tert-butyldiphenylsilyloxy)-4-(tert-butylthio)-4-oxobutyl)-3,3-dimethyltetrahydro-2H-pyran-4-yl acetate

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Chemical Property of (2S,4S,6S)-2-(((2R,6R)-6-((E)-3-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-hydroxybutyl)-2-methoxy-3-oxotetrahydro-2H-pyran-2-yl)-3-methylbut-1-enyl)-4-oxotetrahydro-2H-pyran-2-yl)methyl)-6-((R)-2-(tert-butyldiphenylsilyloxy)-4-(tert-butylthio)-4-oxobutyl)-3,3-dimethyltetrahydro-2H-pyran-4-yl acetate

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Technology Process of (2S,4S,6S)-2-(((2R,6R)-6-((E)-3-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-hydroxybutyl)-2-methoxy-3-oxotetrahydro-2H-pyran-2-yl)-3-methylbut-1-enyl)-4-oxotetrahydro-2H-pyran-2-yl)methyl)-6-((R)-2-(tert-butyldiphenylsilyloxy)-4-(tert-butylthio)-4-oxobutyl)-3,3-dimethyltetrahydro-2H-pyran-4-yl acetate

There total 1 articles about (2S,4S,6S)-2-(((2R,6R)-6-((E)-3-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-hydroxybutyl)-2-methoxy-3-oxotetrahydro-2H-pyran-2-yl)-3-methylbut-1-enyl)-4-oxotetrahydro-2H-pyran-2-yl)methyl)-6-((R)-2-(tert-butyldiphenylsilyloxy)-4-(tert-butylthio)-4-oxobutyl)-3,3-dimethyltetrahydro-2H-pyran-4-yl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1239579-36-2
(2S,4S,6S)-2-(((2R,6R)-6-((E)-3-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-(4-methoxybenzyloxy)butyl)-2-methoxy-3-oxotetrahydro-2H-pyran-2-yl)-3-methylbut-1-enyl)-4-oxotetrahydro-2H-pyran-2-yl)methyl)-6-((R)-2-(tert-butyldiphenylsilyloxy)-4-(tert-butylthio)-4-oxobutyl)-3,3-dimethyltetrahydro-2H-pyran-4-yl acetate

: 1239579-41-9
(2S,4S,6S)-2-(((2R,6R)-6-((E)-3-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-hydroxybutyl)-2-methoxy-3-oxotetrahydro-2H-pyran-2-yl)-3-methylbut-1-enyl)-4-oxotetrahydro-2H-pyran-2-yl)methyl)-6-((R)-2-(tert-butyldiphenylsilyloxy)-4-(tert-butylthio)-4-oxobutyl)-3,3-dimethyltetrahydro-2H-pyran-4-yl acetate

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 0 ℃; for 2h; pH=7; Inert atmosphere; aq. phosphate buffer;
DOI:10.1002/anie.201001200

Reference yield: 83.0%

: 1239579-41-9
(2S,4S,6S)-2-(((2R,6R)-6-((E)-3-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-hydroxybutyl)-2-methoxy-3-oxotetrahydro-2H-pyran-2-yl)-3-methylbut-1-enyl)-4-oxotetrahydro-2H-pyran-2-yl)methyl)-6-((R)-2-(tert-butyldiphenylsilyloxy)-4-(tert-butylthio)-4-oxobutyl)-3,3-dimethyltetrahydro-2H-pyran-4-yl acetate

: 1239579-37-3
(R)-4-((2S,4S,6S)-4-acetoxy-6-(((2R,6R)-6-((E)-3-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-hydroxybutyl)-2-methoxy-3-oxotetrahydro-2H-pyran-2-yl)-3-methylbut-1-enyl)-4-oxotetrahydro-2H-pyran-2-yl)methyl)-5,5-dimethyltetrahydro-2H-pyran-2-yl)-3-(tert-butyldiphenylsilyloxy)butanoic acid

Guidance literature:: With water; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; at 0 - 20 ℃; for 9h; Inert atmosphere;
DOI:10.1002/anie.201001200