(+)-(2S,3S)-methyl 2-phenyl-3-(2-trimethylsilylphenylsulfanyl)butanoate

Base Information

Chemical Name:(+)-(2S,3S)-methyl 2-phenyl-3-(2-trimethylsilylphenylsulfanyl)butanoate
CAS No.:392668-22-3
Molecular Formula:C₂₀H₂₆O₂SSi
Molecular Weight:358.577
Hs Code.:

Synonyms:(+)-(2S,3S)-methyl 2-phenyl-3-(2-trimethylsilylphenylsulfanyl)butanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+)-(2S,3S)-methyl 2-phenyl-3-(2-trimethylsilylphenylsulfanyl)butanoate

Chemical Property:

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Technology Process of (+)-(2S,3S)-methyl 2-phenyl-3-(2-trimethylsilylphenylsulfanyl)butanoate

There total 1 articles about (+)-(2S,3S)-methyl 2-phenyl-3-(2-trimethylsilylphenylsulfanyl)butanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 50415-85-5
(E)-benzeneacetic acid, α-ethylidene, methyl ester

: 33356-45-5
2-(Trimethylsilyl)benzenethiol

: (2R,3R)-methyl 2-phenyl-3-(2-trimethylsilylphenyl-sulfanyl)butanoate

: 392668-22-3
(+)-(2S,3S)-methyl 2-phenyl-3-(2-trimethylsilylphenylsulfanyl)butanoate

Guidance literature:: With chiral amino ether-lithium thiolate; In hexane; toluene; at -78 ℃; for 33h; Title compound not separated from byproducts.;
DOI:10.1021/jo015879v

Reference yield:

: 392668-22-3
(+)-(2S,3S)-methyl 2-phenyl-3-(2-trimethylsilylphenylsulfanyl)butanoate

: 2294-71-5,26164-15-8,127641-43-4,88424-45-7
(-)-(R)-2-phenyl-butyric acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: TfOH / toluene / 0.17 h / 20 °C

2: Raney Ni W-4; NaPH₂O₂; acetate buffer / methanol / 0.5 h / 20 °C

With sodium hypophosphite; trifluorormethanesulfonic acid; acetate buffer; Raney Ni W-4; In methanol; toluene;
DOI:10.1021/jo015879v

Reference yield:

: 392668-22-3
(+)-(2S,3S)-methyl 2-phenyl-3-(2-trimethylsilylphenylsulfanyl)butanoate

: (2R,3R)-methyl 2-phenyl-3-phenylsulfanylbutanoate

: 392668-24-5
(+)-(2S,3S)-methyl 2-phenyl-3-phenylsulfanylbutanoate

Guidance literature:: With trifluorormethanesulfonic acid; In toluene; at 20 ℃; for 0.166667h; Title compound not separated from byproducts.;
DOI:10.1021/jo015879v