33356-45-5

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 20965-36-0 2-(phenylthio)tetrahydro-2H-pyran 
• 6320-02-1 o-bromothiophenol 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 108-98-5 thiophenol 
• 497180-95-7 O-(2-trimethylsilylphenyl)-N,N-dimethylaminothiocarbamate 
• 497180-98-0 S-(2-trimethylsilylphenyl)-N,N-dimethylaminothiocarbamate 
• 84998-55-0 o-Bromphenyl-trimethylsilylthioether 
• 117526-61-1 2-(trimethylsilyl)phenyl-2-tetrahydropyranyl sulfide 
• 18036-83-4 o-(trimethylsilyl)phenol trimethylsilyl ether 
• 95-56-7 2-hydroxybromobenzene 
• 15288-53-6 o-(trimethylsilyl)phenol 

Downstream Products

• 119327-26-3 C₂₄H₃₁OPS₂Si₂ 
• 119327-24-1 2,2',2-trimercapto-3,3',3-tris(trimethylsilyl)triphenylphosphine 
• 119327-27-4 C₂₇H₃₉OPS₃Si₃ 
• 119327-23-0 6,6'-(phenylphosphine)bis(2-(trimethylsilyl)benzenethiol) 
• 119327-25-2 2-(diphenylphosphinyl)-6-(trimethylsilyl)benzenethiol 
• 392668-12-1 (-)-(2S,3S)-methyl 2-methyl-3-(2-trimethylsilylphenylsulfanyl)butanoate 

Relevant academic research and scientific papers

Synthesis and structural Characterization of 12, an Unusual Example of a 'Paddle-Wheel' Dodecametallic Thiolate Cluster

Treatment of PF6 with the sterically-hindered thiolate ligand 2-(trimethylsilyl)benzenethiol, HSC6H4-o-SiMe3, affords red-orange crystals of 12, a dodecametallic thiolate cluster with a "paddle-wheel' C12S12 core.

Development of Odorless Thiols and Sulfides and Their Applications to Organic Synthesis

Development of new odorless thiols (dodecanethiol, 4-n- heptylphenylmethanethiol, 4-trimethylsilylphenylmethanethiol, 4-trimethylsilylbenzenethiol) and an odorless sulfide (1-methylsulfanyldodecane) and their applications to dealkylation, Michael addition, Swern oxidation, and Corey-Kim oxidation are described.

Synthetic equivalents of benzenethiol and benzyl mercaptan having faint smell: Odor reducing effect of trialkylsilyl group

Syntheses and odor tests of the trialkylsilylated benzyl mercaptans and benzenethiols have revealed that the trimethylsilyl substituent on the benzene ring has a remarkable effect in reducing the foul smell of the parent benzyl mercaptan and benzenethiol.

An Effective and Selective Synthesis of Sterically Crowded Benzotrithioles from Benzodithiastannoles via Benzotrithiole 2-Oxides

Sterically crowded benzotrithioles were efficiently and selectively prepared by the reduction of corresponding benzotrithiole 2-oxides which were readily obtained on treatment of benzodithiastannoles, synthetic equivalents of benzenedithiols, with thionyl chloride.

Method of preparation of organosilyl substituted aromatic or heteroaromatic compounds

An improved method of preparing an ortho-, meta- or para-silyl aromatic or heteroaromatic compound represented by the formula STR1 wherein X is oxygen or sulfur, R1 represents the atoms necessary to complete an unsubstituted or substituted arom