1,3-di-N-benzyl-5,6-O-cyclohexylidene-2-deoxy-4-O-(2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1,3-di-N-methoxycarbonylstreptamine

Base Information

Chemical Name:1,3-di-N-benzyl-5,6-O-cyclohexylidene-2-deoxy-4-O-(2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1,3-di-N-methoxycarbonylstreptamine
CAS No.:110537-73-0
Molecular Formula:C₃₆H₄₆N₂O₁₀
Molecular Weight:666.769
Hs Code.:

Synonyms:1,3-di-N-benzyl-5,6-O-cyclohexylidene-2-deoxy-4-O-(2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1,3-di-N-methoxycarbonylstreptamine

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Chemical Property of 1,3-di-N-benzyl-5,6-O-cyclohexylidene-2-deoxy-4-O-(2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1,3-di-N-methoxycarbonylstreptamine

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Technology Process of 1,3-di-N-benzyl-5,6-O-cyclohexylidene-2-deoxy-4-O-(2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1,3-di-N-methoxycarbonylstreptamine

There total 8 articles about 1,3-di-N-benzyl-5,6-O-cyclohexylidene-2-deoxy-4-O-(2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1,3-di-N-methoxycarbonylstreptamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 110537-72-9
1,3-di-N-benzyl-5,6-O-cyclohexylidene-2-deoxy-4-O-(4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1,3-di-N-methoxycarbonylstreptamine

: 110537-73-0
1,3-di-N-benzyl-5,6-O-cyclohexylidene-2-deoxy-4-O-(2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1,3-di-N-methoxycarbonylstreptamine

Guidance literature:: With sodium methylate; In methanol;
DOI:10.1016/S0008-6215(00)90217-9

Reference yield:

: 82472-81-9
3',4':5,6-di-O-cyclohexylidene-tetra-N-methoxycarbonylneamine

: 110537-73-0
1,3-di-N-benzyl-5,6-O-cyclohexylidene-2-deoxy-4-O-(2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1,3-di-N-methoxycarbonylstreptamine

Guidance literature:: Multi-step reaction with 7 steps

1: 83 percent / sodium hydride, N,N-dimethylformamide / 24 h / 25 °C

2: 81 percent / 1:1 acetic acid / 7 h / 56 °C

3: periodic acid / tetrahydrofuran / 1 h

4: 0.15 g / triethylamine / methanol / 24 h / 25 °C

5: 81 percent / sodium methoxide / methanol / 2 h / 70 °C

6: 75 percent / boron trifluoride etherate, triethylamine / CHCl₃ / 2 h / -5 °C

7: 95 percent / NaOMe / methanol

With boron trifluoride diethyl etherate; sodium methylate; sodium hydride; acetic acid; periodic acid; triethylamine; N,N-dimethyl-formamide; In tetrahydrofuran; methanol; chloroform;
DOI:10.1016/S0008-6215(00)90217-9

Reference yield:

: 110537-69-4
tetra-N-benzyl-3',4':5,6-di-O-cyclohexylidene-tetra-N-methoxycarbonylneamine

: 110537-73-0
1,3-di-N-benzyl-5,6-O-cyclohexylidene-2-deoxy-4-O-(2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1,3-di-N-methoxycarbonylstreptamine

Guidance literature:: Multi-step reaction with 6 steps

1: 81 percent / 1:1 acetic acid / 7 h / 56 °C

2: periodic acid / tetrahydrofuran / 1 h

3: 0.15 g / triethylamine / methanol / 24 h / 25 °C

4: 81 percent / sodium methoxide / methanol / 2 h / 70 °C

5: 75 percent / boron trifluoride etherate, triethylamine / CHCl₃ / 2 h / -5 °C

6: 95 percent / NaOMe / methanol

With boron trifluoride diethyl etherate; sodium methylate; acetic acid; periodic acid; triethylamine; In tetrahydrofuran; methanol; chloroform;
DOI:10.1016/S0008-6215(00)90217-9