allyl 4,6-O-benzylidene-GlcNAlloc

Base Information

Chemical Name:allyl 4,6-O-benzylidene-GlcNAlloc
CAS No.:391860-75-6
Molecular Formula:C₂₀H₂₅NO₇
Molecular Weight:391.421
Hs Code.:

Synonyms:allyl 4,6-O-benzylidene-GlcNAlloc

Suppliers and Price of allyl 4,6-O-benzylidene-GlcNAlloc

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of allyl 4,6-O-benzylidene-GlcNAlloc

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of allyl 4,6-O-benzylidene-GlcNAlloc

There total 5 articles about allyl 4,6-O-benzylidene-GlcNAlloc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 1125-88-8
benzaldehyde dimethyl acetal

: 146934-02-3
2-N-Allyloxycarbonyl-2-amino-2-deoxy-D-glucopyranose

: 107-18-6
allyl alcohol

: 391860-75-6
allyl 4,6-O-benzylidene-GlcNAlloc

Guidance literature:: 2-N-Allyloxycarbonyl-2-amino-2-deoxy-D-glucopyranose; allyl alcohol; With chloro-trimethyl-silane; at 20 ℃; for 72h;

benzaldehyde dimethyl acetal; With toluene-4-sulfonic acid; In acetonitrile; at 20 ℃;
DOI:10.1271/bbb.66.211

Reference yield:

: ((2R,4aR,7R,8R,8aS)-8-Hydroxy-2-phenyl-6-prop-2-ynyloxy-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-carbamic acid allyl ester

: 391860-75-6
allyl 4,6-O-benzylidene-GlcNAlloc

Guidance literature:: Multi-step reaction with 2 steps

1.1: Co₂(CO)8 / CH₂Cl₂ / 20 °C

1.2: 100 percent / CF₃COOH; water / CH₂Cl₂ / 1 h / 20 °C

2.1: chlorotrimethylsilane / 72 h / 20 °C

2.2: 66 percent / p-toluenesulfonic acid / acetonitrile / 20 °C

With chloro-trimethyl-silane; dicobalt octacarbonyl; In dichloromethane; 2.1: Fischer glycosidation;
DOI:10.1271/bbb.66.211

Reference yield:

: 1078691-95-8
(+)-D-glucosamine hydrochloride

: 391860-75-6
allyl 4,6-O-benzylidene-GlcNAlloc

Guidance literature:: Multi-step reaction with 3 steps

1: NaHCO₃; water

2: Dowex 50 W X₈ 200-400 mesh / 80 °C

3: p-TsOH

With Dowex 50 W X₈ 200-400 mesh; water; sodium hydrogencarbonate; toluene-4-sulfonic acid;
DOI:10.1016/S0040-4039(01)01619-7