5-[4-(trimethylsilyl)ethynylphenyl]-13,17-diethyl-2,3,7,8,12,18-hexamethyl-porphyrin zinc

Base Information

Chemical Name:5-[4-(trimethylsilyl)ethynylphenyl]-13,17-diethyl-2,3,7,8,12,18-hexamethyl-porphyrin zinc
CAS No.:1182371-09-0
Molecular Formula:C₄₁H₄₄N₄SiZn
Molecular Weight:686.303
Hs Code.:

Synonyms:5-[4-(trimethylsilyl)ethynylphenyl]-13,17-diethyl-2,3,7,8,12,18-hexamethyl-porphyrin zinc

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Chemical Property of 5-[4-(trimethylsilyl)ethynylphenyl]-13,17-diethyl-2,3,7,8,12,18-hexamethyl-porphyrin zinc

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Technology Process of 5-[4-(trimethylsilyl)ethynylphenyl]-13,17-diethyl-2,3,7,8,12,18-hexamethyl-porphyrin zinc

There total 1 articles about 5-[4-(trimethylsilyl)ethynylphenyl]-13,17-diethyl-2,3,7,8,12,18-hexamethyl-porphyrin zinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: zinc(II) acetate tetrahydrate

: 5-[4-(trimethylsilyl)ethynylphenyl]-13,17-diethyl-2,3,7,8,12,18-hexamethyl-porphyrin

: 1182371-09-0
5-[4-(trimethylsilyl)ethynylphenyl]-13,17-diethyl-2,3,7,8,12,18-hexamethyl-porphyrin zinc

Guidance literature:: With CH₃ONa; In methanol; chloroform; (Ar); Schlenk technique; soln. of ligand and Zn salt in CHCl3/MeOH was refluxed for 90 min in presence of CH3ONa; UV monitoring; evapd. (vac.); dissolved in CH2Cl2; washed (H2O); dried (MgSO4); evapd. (vac.); chromd. (silica, CH2Cl2); evapd.;
DOI:10.1021/ic900840w

Reference yield: 78.0%

: 1182371-09-0
5-[4-(trimethylsilyl)ethynylphenyl]-13,17-diethyl-2,3,7,8,12,18-hexamethyl-porphyrin zinc

: 1182371-21-6
5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethylporphyrinato zinc(II)

Guidance literature:: With Bu₄NF; In tetrahydrofuran; (Ar); Schlenk technique; soln. of Bu4NF in THF was added to soln. of Zn complex in THF; stirred at room temp. for 12 h; evapd. (vac.); dissolved in CH2Cl2; washed (satd. NH4Cl, H2O); dried (MgSO4); chromd. (silica, CH2Cl2);
DOI:10.1021/ic900840w