<<9-<4-<1-<(p-toluenesulfonyloxy)imino>-2,2,2-trifluoroethyl>phenyl>nonyl>oxy>-tert-butyldimethylsilane

Base Information

Chemical Name:<<9-<4-<1-<(p-toluenesulfonyloxy)imino>-2,2,2-trifluoroethyl>phenyl>nonyl>oxy>-tert-butyldimethylsilane
CAS No.:156661-68-6
Molecular Formula:C₃₀H₄₄F₃NO₄SSi
Molecular Weight:599.83
Hs Code.:

Synonyms:<<9-<4-<1-<(p-toluenesulfonyloxy)imino>-2,2,2-trifluoroethyl>phenyl>nonyl>oxy>-tert-butyldimethylsilane

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Chemical Property of <<9-<4-<1-<(p-toluenesulfonyloxy)imino>-2,2,2-trifluoroethyl>phenyl>nonyl>oxy>-tert-butyldimethylsilane

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Technology Process of <<9-<4-<1-<(p-toluenesulfonyloxy)imino>-2,2,2-trifluoroethyl>phenyl>nonyl>oxy>-tert-butyldimethylsilane

There total 9 articles about <<9-<4-<1-<(p-toluenesulfonyloxy)imino>-2,2,2-trifluoroethyl>phenyl>nonyl>oxy>-tert-butyldimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 98-59-9
p-toluenesulfonyl chloride

: 156661-67-5
<<9-<4-<1-(hydroxyimino)-2,2,2-trifluoroethyl>phenyl>nonyl>oxy>-tert-butyldimethylsilane

: 156661-68-6
<<9-<4-<1-<(p-toluenesulfonyloxy)imino>-2,2,2-trifluoroethyl>phenyl>nonyl>oxy>-tert-butyldimethylsilane

Guidance literature:: With pyridine; for 1h; Heating;
DOI:10.1016/S0040-4020(01)90398-9

Reference yield:

: 1122-91-4
4-bromo-benzaldehyde

: 156661-68-6
<<9-<4-<1-<(p-toluenesulfonyloxy)imino>-2,2,2-trifluoroethyl>phenyl>nonyl>oxy>-tert-butyldimethylsilane

Guidance literature:: Multi-step reaction with 7 steps

1: 47 percent / 2.5M n-buthyllithium / tetrahydrofuran; dimethylsulfoxide; hexane / 15 h / 0 - 23 °C

2: 89 percent / H₂ / PtO₂ / ethanol; acetic acid / 120 h / 3102.9 Torr / Ambient temperature

3: 96 percent / lithium aluminum hydride / tetrahydrofuran / 12 h / 0 - 70 °C

4: 96 percent / imidazole / dimethylformamide / 48 h / 50 °C

5: 49 percent / 2.5M n-butyllithium / diethyl ether; hexane / 3 h / -50 °C

6: 54 percent / NH₂OH*HCl, NaOH / ethanol / 16 h / Heating

7: 54 percent / pyridine / 1 h / Heating

With pyridine; 1H-imidazole; sodium hydroxide; lithium aluminium tetrahydride; n-butyllithium; hydroxylamine hydrochloride; hydrogen; platinum(IV) oxide; In tetrahydrofuran; diethyl ether; ethanol; hexane; acetic acid; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)90398-9

Reference yield:

: ω-carbethoxyheptyl triphenyl phosphonium bromide

: 156661-68-6
<<9-<4-<1-<(p-toluenesulfonyloxy)imino>-2,2,2-trifluoroethyl>phenyl>nonyl>oxy>-tert-butyldimethylsilane

Guidance literature:: Multi-step reaction with 7 steps

1: 47 percent / 2.5M n-buthyllithium / tetrahydrofuran; dimethylsulfoxide; hexane / 15 h / 0 - 23 °C

2: 89 percent / H₂ / PtO₂ / ethanol; acetic acid / 120 h / 3102.9 Torr / Ambient temperature

3: 96 percent / lithium aluminum hydride / tetrahydrofuran / 12 h / 0 - 70 °C

4: 96 percent / imidazole / dimethylformamide / 48 h / 50 °C

5: 49 percent / 2.5M n-butyllithium / diethyl ether; hexane / 3 h / -50 °C

6: 54 percent / NH₂OH*HCl, NaOH / ethanol / 16 h / Heating

7: 54 percent / pyridine / 1 h / Heating

With pyridine; 1H-imidazole; sodium hydroxide; lithium aluminium tetrahydride; n-butyllithium; hydroxylamine hydrochloride; hydrogen; platinum(IV) oxide; In tetrahydrofuran; diethyl ether; ethanol; hexane; acetic acid; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)90398-9