triisopropylsilane-d¹

Base Information

• Chemical Name: triisopropylsilane-d¹
• CAS No.: 139408-37-0
• Molecular Formula: C₉H₂₂Si
• Molecular Weight: 159.351
• Mol file: 139408-37-0.mol

Synonyms:triisopropylsilane-d¹

Chemical Property of triisopropylsilane-d¹

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of triisopropylsilane-d¹

There total 1 articles about triisopropylsilane-d¹ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C21H48PSi(1+)*C24BF20(1-) → C24BF20(1-)*C12H27(2)HP(1+) (872885-10-4) + triisopropylsilane-d1 (139408-37-0)

Guidance literature:

With deuterium; In chlorobenzene; at 90 ℃; for 8h; under 3000.3 Torr;

DOI:10.1039/c4cc05905k

Reference yield: 92.0%

cyclopropylbenzene (873-49-4) + triisopropylsilane-d1 (139408-37-0) → C18H30(2)H2Si

Guidance literature:

triisopropylsilane-d¹; With tri(phenyl)methylium closo-7,8,9,10,11,12-hexabromocarboranate; In benzene; at 20 ℃; for 0.0166667h; Glovebox; Inert atmosphere;

cyclopropylbenzene; In benzene; at 20 ℃; for 0.25h; regioselective reaction; Glovebox; Inert atmosphere;

DOI:10.1021/acs.orglett.0c00173

Reference yield: 77.0%

8-methylenebicyclo<5.1.0>octane (54211-15-3) + benzaldehyde (100-52-7) + triisopropylsilane-d1 (139408-37-0) → C25H41(2)HOSi (1246993-34-9)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel⁽⁰⁾; n-butyllithium; N,N'-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene hydrochloride; In tetrahydrofuran; hexane; at 20 ℃; for 15h; regioselective reaction; Inert atmosphere;

DOI:10.1021/ol101838q

Downstream raw materials:

C₉H₂₁Si⁽¹⁺⁾

C₂₅H₄₁⁽²⁾HOSi

<α-2H>-4-methylbenzyl alcohol