methyl 1-{2-[N-(4-methoxybenzoyl)-N'-methylsulfanylthiocarbonyl-N'-phenylhydrazino]ethyl}-2,5-cyclohexadiene carboxylate

Base Information

Chemical Name:methyl 1-{2-[N-(4-methoxybenzoyl)-N'-methylsulfanylthiocarbonyl-N'-phenylhydrazino]ethyl}-2,5-cyclohexadiene carboxylate
CAS No.:850093-77-5
Molecular Formula:C₂₆H₂₈N₂O₄S₂
Molecular Weight:496.651
Hs Code.:

Synonyms:methyl 1-{2-[N-(4-methoxybenzoyl)-N'-methylsulfanylthiocarbonyl-N'-phenylhydrazino]ethyl}-2,5-cyclohexadiene carboxylate

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Chemical Property of methyl 1-{2-[N-(4-methoxybenzoyl)-N'-methylsulfanylthiocarbonyl-N'-phenylhydrazino]ethyl}-2,5-cyclohexadiene carboxylate

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Technology Process of methyl 1-{2-[N-(4-methoxybenzoyl)-N'-methylsulfanylthiocarbonyl-N'-phenylhydrazino]ethyl}-2,5-cyclohexadiene carboxylate

There total 5 articles about methyl 1-{2-[N-(4-methoxybenzoyl)-N'-methylsulfanylthiocarbonyl-N'-phenylhydrazino]ethyl}-2,5-cyclohexadiene carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 850093-76-4
methyl 1-[2-(N'-methylsulfanylthiocarbonyl-N'-phenylhydrazino)ethyl]-2,5-cyclohexadiene carboxylate

: 100-07-2
4-methoxy-benzoyl chloride

: 850093-77-5
methyl 1-{2-[N-(4-methoxybenzoyl)-N'-methylsulfanylthiocarbonyl-N'-phenylhydrazino]ethyl}-2,5-cyclohexadiene carboxylate

Guidance literature:: With pyridine; dmap; at 80 ℃; for 12h;
DOI:10.1039/b416763e

Reference yield:

: 850093-58-2
1-[1,3]dioxolan-2-ylmethyl-cyclohexa-2,5-dienecarboxylic acid methyl ester

: 850093-77-5
methyl 1-{2-[N-(4-methoxybenzoyl)-N'-methylsulfanylthiocarbonyl-N'-phenylhydrazino]ethyl}-2,5-cyclohexadiene carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: aq. HCOOH / 0 °C

2: AcOH / methanol / 20 °C

3: NaBH₃CN; AcOH / methanol / 20 °C / pH 4 - 5

4: 82 percent / pyridine; DMAP / 12 h / 80 °C

With pyridine; dmap; formic acid; sodium cyanoborohydride; acetic acid; In methanol;
DOI:10.1039/b416763e

Reference yield:

: 850093-63-9
1-(1,3-dioxolan-2-ylmethyl)-2,5-cyclohexadiene-1-carboxylic acid

: 850093-77-5
methyl 1-{2-[N-(4-methoxybenzoyl)-N'-methylsulfanylthiocarbonyl-N'-phenylhydrazino]ethyl}-2,5-cyclohexadiene carboxylate

Guidance literature:: Multi-step reaction with 5 steps

1: 100 percent / DBU / tetrahydrofuran / 3 h / 20 °C

2: aq. HCOOH / 0 °C

3: AcOH / methanol / 20 °C

4: NaBH₃CN; AcOH / methanol / 20 °C / pH 4 - 5

5: 82 percent / pyridine; DMAP / 12 h / 80 °C

With pyridine; dmap; formic acid; sodium cyanoborohydride; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; methanol;
DOI:10.1039/b416763e