d₁₀-benzophenone imine

Base Information

• Chemical Name: d₁₀-benzophenone imine
• CAS No.: 1170155-68-6
• Molecular Formula: C₁₃H₁₁N
• Molecular Weight: 191.158
• Mol file: 1170155-68-6.mol

Synonyms:d₁₀-benzophenone imine

Chemical Property of d₁₀-benzophenone imine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of d₁₀-benzophenone imine

There total 3 articles about d₁₀-benzophenone imine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

perdeuterated cyanobenzene (2102-15-0) + phenylmagnesium bromide-d5 (84783-81-3) → d10-benzophenone imine (1170155-68-6)

Guidance literature:

In diethyl ether; for 5h; Heating / reflux;

Reference yield:

bromobenzene-d5 (4165-57-5) → d10-benzophenone imine (1170155-68-6)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium carbonate; palladium diacetate; 1,1'-bis-(diphenylphosphino)ferrocene / 16 h / 120 °C / Schlenk technique; Inert atmosphere

2: tetrahydrofuran / 12 h / 80 °C / Schlenk technique; Inert atmosphere

With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium carbonate; In tetrahydrofuran;

DOI:10.1002/anie.201402575

Reference yield:

(2H10)benzophenone (22583-75-1) → d10-benzophenone imine (1170155-68-6)

Guidance literature:

With ammonia; titanium tetrachloride; In toluene;

DOI:10.1021/acs.analchem.7b03996

upstream raw materials:

perdeuterated cyanobenzene

phenylmagnesium bromide-d5

bromobenzene-d5

(2H₁₀)benzophenone

Downstream raw materials:

d11-C,C-diphenyl-methylamine

C₂₇H₁₀⁽²⁾H₉N