dimethyl (2'E,1'R)-2-[1'-acetoxy-4'-(t-butyldiphenylsilyloxy)-2'-butenyl]-2-benzylmalonate

Base Information

Chemical Name:dimethyl (2'E,1'R)-2-[1'-acetoxy-4'-(t-butyldiphenylsilyloxy)-2'-butenyl]-2-benzylmalonate
CAS No.:342906-84-7
Molecular Formula:C₃₄H₄₀O₇Si
Molecular Weight:588.773
Hs Code.:

Synonyms:dimethyl (2'E,1'R)-2-[1'-acetoxy-4'-(t-butyldiphenylsilyloxy)-2'-butenyl]-2-benzylmalonate

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Chemical Property of dimethyl (2'E,1'R)-2-[1'-acetoxy-4'-(t-butyldiphenylsilyloxy)-2'-butenyl]-2-benzylmalonate

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Technology Process of dimethyl (2'E,1'R)-2-[1'-acetoxy-4'-(t-butyldiphenylsilyloxy)-2'-butenyl]-2-benzylmalonate

There total 2 articles about dimethyl (2'E,1'R)-2-[1'-acetoxy-4'-(t-butyldiphenylsilyloxy)-2'-butenyl]-2-benzylmalonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 49769-78-0
2-benzyl-malonic acid dimethyl ester

: 169689-20-7
(E)-1,1-diacetoxy-4-(t-butyldiphenylsilyloxy)-2-butene

: 2-[(E)-(S)-1-Acetoxy-4-(tert-butyl-diphenyl-silanyloxy)-but-2-enyl]-2-benzyl-malonic acid dimethyl ester

: 342906-84-7
dimethyl (2'E,1'R)-2-[1'-acetoxy-4'-(t-butyldiphenylsilyloxy)-2'-butenyl]-2-benzylmalonate

Guidance literature:: 2-benzyl-malonic acid dimethyl ester; With sodium hydride; In tetrahydrofuran; at 20 ℃;

(E)-1,1-diacetoxy-4-(t-butyldiphenylsilyloxy)-2-butene; With Π-palladium chloride dimer; (1R,2R)-1,2-bis[(2-diphenylphosphanyl)benzoylamino]cyclohexane; In tetrahydrofuran; at 0 ℃; for 3h; Further stages. Title compound not separated from byproducts.;
DOI:10.1021/ja003775g

Reference yield:

: 169689-20-7
(E)-1,1-diacetoxy-4-(t-butyldiphenylsilyloxy)-2-butene

: dimethyl sodiobenzylmalonate

: 2-[(E)-(S)-1-Acetoxy-4-(tert-butyl-diphenyl-silanyloxy)-but-2-enyl]-2-benzyl-malonic acid dimethyl ester

: 342906-84-7
dimethyl (2'E,1'R)-2-[1'-acetoxy-4'-(t-butyldiphenylsilyloxy)-2'-butenyl]-2-benzylmalonate

Guidance literature:: With bis(η3-allyl-μ-chloropalladium(II)); (1R,2R)-1,2-bis[(2-diphenylphosphanyl)benzoylamino]cyclohexane; In tetrahydrofuran; at 0 ℃; for 2h; Title compound not separated from byproducts.;
DOI:10.1021/ja003774o