cis-dimethyl(phenyl)(triphenylphosphine)gold(III)

Base Information

• Chemical Name: cis-dimethyl(phenyl)(triphenylphosphine)gold(III)
• CAS No.: 42029-61-8
• Molecular Formula: C₂₆H₂₆AuP
• Molecular Weight: 566.433
• Mol file: 42029-61-8.mol

Synonyms:cis-dimethyl(phenyl)(triphenylphosphine)gold(III)

Chemical Property of cis-dimethyl(phenyl)(triphenylphosphine)gold(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-dimethyl(phenyl)(triphenylphosphine)gold(III)

There total 4 articles about cis-dimethyl(phenyl)(triphenylphosphine)gold(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

lithium trimethyl(phenyl)aurate(III) → trimethyl(triphenylphosphine)gold(III) + cis-dimethyl(phenyl)(triphenylphosphine)gold(III) (42029-61-8)

Guidance literature:

With PPh₃; H₂O; In benzene; byproducts: CH4, C2H6; (N2 or Ar), soln. evacuated, H2O added; evapd., extd. (pentane); NMR;

DOI:10.1016/0022-328X(92)80159-U

Reference yield: 55.0%

cis-dimethyl(iodo)(triphenylphosphine)gold(III) → cis-dimethyl(phenyl)(triphenylphosphine)gold(III) (42029-61-8)

Guidance literature:

With phenylmagnesium bromide; In diethyl ether; byproducts: MgBrI; etheral suspn. of the Au-complex treated with an excess of the Grignard soln. at 0°C, stirred for 3 h at room temp.; slowly hydrolyzed with deoxygenated water at 0°C, ether layer and benzene extracts collected, solvents evapd., recrystd. from benzene/pentane, elem. anal.;

DOI:10.1021/om00123a012

Reference yield:

Au(CH3)2I(P(C6H5)3) → cis-dimethyl(phenyl)(triphenylphosphine)gold(III) (42029-61-8)

Guidance literature:

With PhMgHal; In not given; according to S. Komiya and A. Shibue, Organometallics, 4 (1985) 684; S. Komiya, T. A. Albright, R. Hoffmann, and J. K. Kochi, J. Am. Chem. Soc., 98 (1986) 7255; elem. anal.;

DOI:10.1016/0022-328X(87)83038-3

upstream raw materials:

phenylmagnesium bromide