N-(11-undecanoic acid)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide

Base Information

• Chemical Name: N-(11-undecanoic acid)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide
• CAS No.: 1019334-92-9
• Molecular Formula: C₄₀H₆₉N₃O₅
• Molecular Weight: 672.005
• Mol file: 1019334-92-9.mol

Synonyms:N-(11-undecanoic acid)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide

Chemical Property of N-(11-undecanoic acid)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(11-undecanoic acid)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide

There total 4 articles about N-(11-undecanoic acid)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

N-(ethyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide (1415681-32-1) → N-(11-undecanoic acid)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide (1019334-92-9)

Guidance literature:

With water; lithium hydroxide; In 1,4-dioxane; at 20 ℃;

DOI:10.1002/anie.201204727

Reference yield:

methyl-3,5-bis-n-decylaminocarbonyl-benzoate (1415681-30-9) → N-(11-undecanoic acid)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide (1019334-92-9)

Guidance literature:

Multi-step reaction with 3 steps

1: lithium hydroxide monohydrate / methanol; water / 48 h / 20 °C

2: dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / chloroform / 48 h / Inert atmosphere; Cooling with ice

3: lithium hydroxide; water / 1,4-dioxane / 20 °C

With dmap; lithium hydroxide monohydrate; water; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; lithium hydroxide; In 1,4-dioxane; methanol; chloroform; water;

DOI:10.1002/anie.201204727

Reference yield:

1,3,5-tris-(methoxycarbonyl)benzene (2672-58-4) → N-(11-undecanoic acid)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide (1019334-92-9)

Guidance literature:

Multi-step reaction with 6 steps

1: sodium hydroxide / methanol / 21 h / 85 °C

2: N,N-dimethyl-formamide; oxalyl dichloride / tetrahydrofuran / 1.5 h / 20 °C / Inert atmosphere

3: triethylamine / chloroform / 24 h / 20 °C / Inert atmosphere

4: lithium hydroxide monohydrate / methanol; water / 48 h / 20 °C

5: dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / chloroform / 48 h / Inert atmosphere; Cooling with ice

6: lithium hydroxide; water / 1,4-dioxane / 20 °C

With dmap; lithium hydroxide monohydrate; oxalyl dichloride; water; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; N,N-dimethyl-formamide; sodium hydroxide; lithium hydroxide; In tetrahydrofuran; 1,4-dioxane; methanol; chloroform; water;

DOI:10.1002/anie.201204727

upstream raw materials:

N-(ethyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide

1,3,5-tris-(methoxycarbonyl)benzene

3,5-dicarboxylic acid-1-benzoic acid methyl ester

methyl-3,5-bis-n-decylaminocarbonyl-benzoate

Downstream raw materials:

N-(2,2,3,3,3-pentafluoropropyl 11-undecanoate)-N’,N''-di(n-decyl)benzene-1,3,5-tricarboxamide

N-(2,2,3,3,4,4,4-heptafluorobutyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide

N-(2,2,3,3,4,4,5,5-octafluoropentyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide

N-(2,2,3,3,4,4,5,5,5-nonafluoropentyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide