N-(ethyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide

Base Information

• Chemical Name: N-(ethyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide
• CAS No.: 1415681-32-1
• Molecular Formula: C₄₂H₇₃N₃O₅
• Molecular Weight: 700.059
• Mol file: 1415681-32-1.mol

Synonyms:N-(ethyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide

Chemical Property of N-(ethyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(ethyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide

There total 3 articles about N-(ethyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

11-aminoundecanoic acid ethyl ester (15351-28-7) + 3,5-bis-n-decylaminocarbonyl-benzoic acid (1415681-31-0) → N-(ethyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide (1415681-32-1)

Guidance literature:

With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; In chloroform; for 48h; Inert atmosphere; Cooling with ice;

DOI:10.1002/anie.201204727

Reference yield:

1,3,5-tris-(methoxycarbonyl)benzene (2672-58-4) → N-(ethyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide (1415681-32-1)

Guidance literature:

Multi-step reaction with 5 steps

1: sodium hydroxide / methanol / 21 h / 85 °C

2: N,N-dimethyl-formamide; oxalyl dichloride / tetrahydrofuran / 1.5 h / 20 °C / Inert atmosphere

3: triethylamine / chloroform / 24 h / 20 °C / Inert atmosphere

4: lithium hydroxide monohydrate / methanol; water / 48 h / 20 °C

5: dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / chloroform / 48 h / Inert atmosphere; Cooling with ice

With dmap; lithium hydroxide monohydrate; oxalyl dichloride; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; N,N-dimethyl-formamide; sodium hydroxide; In tetrahydrofuran; methanol; chloroform; water;

DOI:10.1002/anie.201204727

Reference yield:

3,5-dicarboxylic acid-1-benzoic acid methyl ester (18263-95-1) → N-(ethyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide (1415681-32-1)

Guidance literature:

Multi-step reaction with 4 steps

1: N,N-dimethyl-formamide; oxalyl dichloride / tetrahydrofuran / 1.5 h / 20 °C / Inert atmosphere

2: triethylamine / chloroform / 24 h / 20 °C / Inert atmosphere

3: lithium hydroxide monohydrate / methanol; water / 48 h / 20 °C

4: dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / chloroform / 48 h / Inert atmosphere; Cooling with ice

With dmap; lithium hydroxide monohydrate; oxalyl dichloride; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; N,N-dimethyl-formamide; In tetrahydrofuran; methanol; chloroform; water;

DOI:10.1002/anie.201204727

upstream raw materials:

11-aminoundecanoic acid ethyl ester

3,5-bis-n-decylaminocarbonyl-benzoic acid

1,3,5-tris-(methoxycarbonyl)benzene

3,5-dicarboxylic acid-1-benzoic acid methyl ester

Downstream raw materials:

N-(11-undecanoic acid)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide

N-(2,2,3,3,3-pentafluoropropyl 11-undecanoate)-N’,N''-di(n-decyl)benzene-1,3,5-tricarboxamide

N-(2,2,3,3,4,4,4-heptafluorobutyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide

N-(2,2,3,3,4,4,5,5,5-nonafluoropentyl 11-undecanoate)-N’,N”-di(n-decyl)benzene-1,3,5-tricarboxamide