4-((1S,2R,4R)-2-Hydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-1-ylmethylsulfanyl)-4-phenyl-butan-2-one

Base Information

Chemical Name:4-((1S,2R,4R)-2-Hydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-1-ylmethylsulfanyl)-4-phenyl-butan-2-one
CAS No.:185856-02-4
Molecular Formula:C₂₀H₂₈O₂S
Molecular Weight:332.507
Hs Code.:

Synonyms:4-((1S,2R,4R)-2-Hydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-1-ylmethylsulfanyl)-4-phenyl-butan-2-one

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Chemical Property of 4-((1S,2R,4R)-2-Hydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-1-ylmethylsulfanyl)-4-phenyl-butan-2-one

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Technology Process of 4-((1S,2R,4R)-2-Hydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-1-ylmethylsulfanyl)-4-phenyl-butan-2-one

There total 1 articles about 4-((1S,2R,4R)-2-Hydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-1-ylmethylsulfanyl)-4-phenyl-butan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 71242-58-5
(1S,2R,4R)-(-)-10-mercaptoisoboneol

: 1896-62-4
(E)-benzalacetone

: 185856-02-4
4-((1S,2R,4R)-2-Hydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-1-ylmethylsulfanyl)-4-phenyl-butan-2-one

Guidance literature:: With dimethylaluminum chloride; In hexane; dichloromethane; at 0 ℃; for 1h;
DOI:10.1021/ja993546y

Reference yield: 86.0%

: 185856-02-4
4-((1S,2R,4R)-2-Hydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-1-ylmethylsulfanyl)-4-phenyl-butan-2-one

: 185855-96-3
(2S,4R)-4-[(1S,4R)-2-oxobornane-10-sulfenyl]-4-phenyl-2-butanol

Guidance literature:: With dimethylaluminum chloride; In hexane; dichloromethane; at 20 ℃; for 13h;
DOI:10.1021/ja993546y

Reference yield:

: 185856-02-4
4-((1S,2R,4R)-2-Hydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-1-ylmethylsulfanyl)-4-phenyl-butan-2-one

: 2344-70-9,14786-43-7,39516-03-5,22148-86-3
(+)-(S)-4-phenylbutan-2-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / dimethylaluminium chloride / CH₂Cl₂; hexane / 13 h / 20 °C

2: 89 percent / sodium hypophosphite monohydrate; Raney nickel / acetate buffer; ethanol / 0.67 h / 20 °C / pH 5.2

With sodium hypophosphite; dimethylaluminum chloride; nickel; In ethanol; hexane; dichloromethane; acetate buffer; 1: Reduction / 2: reductive desulfurization;
DOI:10.1021/ja993546y