9-methyl-5-(4-nitro-phenyl)-8,9-dihydro-7H-1,3-dioxa-6,7-diaza-cyclohepta[f]indene

Base Information

Chemical Name:9-methyl-5-(4-nitro-phenyl)-8,9-dihydro-7H-1,3-dioxa-6,7-diaza-cyclohepta[f]indene
CAS No.:287379-18-4
Molecular Formula:C₁₇H₁₅N₃O₄
Molecular Weight:325.324
Hs Code.:

9-methyl-5-(4-nitro-phenyl)-8,9-dihydro-7<i>H</i>-1,3-dioxa-6,7-diaza-cyclohepta[<i>f</i>]indene

Synonyms:9-methyl-5-(4-nitro-phenyl)-8,9-dihydro-7H-1,3-dioxa-6,7-diaza-cyclohepta[f]indene

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Chemical Property of 9-methyl-5-(4-nitro-phenyl)-8,9-dihydro-7H-1,3-dioxa-6,7-diaza-cyclohepta[f]indene

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Technology Process of 9-methyl-5-(4-nitro-phenyl)-8,9-dihydro-7H-1,3-dioxa-6,7-diaza-cyclohepta[f]indene

There total 6 articles about 9-methyl-5-(4-nitro-phenyl)-8,9-dihydro-7H-1,3-dioxa-6,7-diaza-cyclohepta[f]indene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 287379-05-9
methanesulfonic acid 2-(6-{(4-nitro-phenyl)-[(pyridine-4-carbonyl)-hydrazono]-methyl}-benzo[1,3]dioxol-5-yl)-propyl ester

: 287379-18-4
9-methyl-5-(4-nitro-phenyl)-8,9-dihydro-7H-1,3-dioxa-6,7-diaza-cyclohepta[f]indene

: [9-methyl-5-(4-nitro-phenyl)-8,9-dihydro-1,3-dioxa-6,7-diaza-cyclohepta[f]inden-7-yl]-pyridin-4-yl-methanone

Guidance literature:: With sodium hydroxide; In methanol;
DOI:10.1016/S0960-894X(00)00117-7

Reference yield:

: 4043-71-4
isosafrole

: 287379-18-4
9-methyl-5-(4-nitro-phenyl)-8,9-dihydro-7H-1,3-dioxa-6,7-diaza-cyclohepta[f]indene

Guidance literature:: Multi-step reaction with 7 steps

1: 80 percent / I₂; Ag₂O / H₂O

2: NaBH₄ / ethanol

3: 60 percent / concd HCl / benzene / 20 °C

4: 93 percent / air; 50 percent aq. NaOH / dimethylformamide; dimethylsulfoxide

5: concd HCl / propan-2-ol

6: Et₃N / CH₂Cl₂

7: 47 percent / 50 percent aq. NaOH / methanol

With hydrogenchloride; sodium hydroxide; sodium tetrahydroborate; air; iodine; triethylamine; silver(l) oxide; In methanol; ethanol; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide; isopropyl alcohol; benzene; 1: Rearrangement / 2: Reduction / 3: Condensation / 4: Oxidation / 5: Condensation / 6: Mesilation / 7: Cyclization;
DOI:10.1016/S0960-894X(00)00117-7

Reference yield:

: 287378-91-0
γ-2-(1,3-benzodioxol-5-yl)propanol

: 287379-18-4
9-methyl-5-(4-nitro-phenyl)-8,9-dihydro-7H-1,3-dioxa-6,7-diaza-cyclohepta[f]indene

Guidance literature:: Multi-step reaction with 5 steps

1: 60 percent / concd HCl / benzene / 20 °C

2: 93 percent / air; 50 percent aq. NaOH / dimethylformamide; dimethylsulfoxide

3: concd HCl / propan-2-ol

4: Et₃N / CH₂Cl₂

5: 47 percent / 50 percent aq. NaOH / methanol

With hydrogenchloride; sodium hydroxide; air; triethylamine; In methanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; isopropyl alcohol; benzene; 1: Condensation / 2: Oxidation / 3: Condensation / 4: Mesilation / 5: Cyclization;
DOI:10.1016/S0960-894X(00)00117-7