C₄₅H₆₈O₅Si₂

Base Information

Chemical Name:C₄₅H₆₈O₅Si₂
CAS No.:1429412-72-5
Molecular Formula:C₄₅H₆₈O₅Si₂
Molecular Weight:745.203
Hs Code.:

C<sub>45</sub>H<sub>68</sub>O<sub>5</sub>Si<sub>2</sub>

Synonyms:C₄₅H₆₈O₅Si₂

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Chemical Property of C₄₅H₆₈O₅Si₂

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Technology Process of C₄₅H₆₈O₅Si₂

There total 27 articles about C₄₅H₆₈O₅Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 1429412-70-3
C₄₅H₆₆O₅Si₂

: 1429412-72-5
C₄₅H₆₈O₅Si₂

: C₄₅H₆₈O₅Si₂

Guidance literature:: With chloro {[(1S,2S)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II); sodium formate; 1-butyl-3-methylimidazolium Tetrafluoroborate; In water; ethyl acetate; at 20 ℃; for 7h;
DOI:10.1039/c3ob27508f

Reference yield:

: 126-30-7
2,2-Dimethyl-1,3-propanediol

: 1429412-72-5
C₄₅H₆₈O₅Si₂

: C₄₅H₆₈O₅Si₂

Guidance literature:: Multi-step reaction with 10 steps

1.1: sodium hydride / nujol; tetrahydrofuran / 16.5 h / 0 °C

1.2: 3.3 h / 0 °C

2.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / 6 h / Reflux

3.1: (R)-Tol-BINAP; tetrabutylammonium triphenyldifluorosilicate; copper(II) bis(trifluoromethanesulfonate) / tetrahydrofuran / 16 h / -78 °C

4.1: methanol; toluene / 1 h / 110 °C / Sealed tube

5.1: potassium carbonate / acetone / 5 h

6.1: hydrogen / isopropyl alcohol / 6 h / 20 °C

7.1: trimethylaluminum / toluene; dichloromethane / 0.58 h / 0 °C

7.2: 1.17 h / 0 °C

8.1: 2,6-dimethylpyridine / dichloromethane / 0.25 h / 0 °C

9.1: triethylamine; palladium bis[bis(diphenylphosphino)ferrocene] dichloride; copper(l) iodide; triphenylphosphine / N,N-dimethyl-formamide / 9 h / 60 °C

10.1: chloro {[(1S,2S)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II); sodium formate; 1-butyl-3-methylimidazolium Tetrafluoroborate / ethyl acetate; water / 7 h / 20 °C

With 2,6-dimethylpyridine; copper(l) iodide; chloro {[(1S,2S)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II); palladium bis[bis(diphenylphosphino)ferrocene] dichloride; (R)-Tol-BINAP; hydrogen; trimethylaluminum; sodium formate; copper(II) bis(trifluoromethanesulfonate); sodium hydride; potassium carbonate; triethylamine; triphenylphosphine; tetrabutylammonium triphenyldifluorosilicate; 1-butyl-3-methylimidazolium Tetrafluoroborate; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; methanol; nujol; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; isopropyl alcohol; acetone; toluene; 3.1: |Mukaiyama Aldol Addition / 10.1: |Noyori Asymmetric Hydrogenation;
DOI:10.1039/c3ob27508f

Reference yield:

: 1429412-35-0
C₂₈H₃₈O₅Si

: 1429412-72-5
C₄₅H₆₈O₅Si₂

: C₄₅H₆₈O₅Si₂

Guidance literature:: Multi-step reaction with 7 steps

1.1: methanol; toluene / 1 h / 110 °C / Sealed tube

2.1: potassium carbonate / acetone / 5 h

3.1: hydrogen / isopropyl alcohol / 6 h / 20 °C

4.1: trimethylaluminum / toluene; dichloromethane / 0.58 h / 0 °C

4.2: 1.17 h / 0 °C

5.1: 2,6-dimethylpyridine / dichloromethane / 0.25 h / 0 °C

6.1: triethylamine; palladium bis[bis(diphenylphosphino)ferrocene] dichloride; copper(l) iodide; triphenylphosphine / N,N-dimethyl-formamide / 9 h / 60 °C

7.1: chloro {[(1S,2S)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II); sodium formate; 1-butyl-3-methylimidazolium Tetrafluoroborate / ethyl acetate; water / 7 h / 20 °C

With 2,6-dimethylpyridine; copper(l) iodide; chloro {[(1S,2S)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II); palladium bis[bis(diphenylphosphino)ferrocene] dichloride; hydrogen; trimethylaluminum; sodium formate; potassium carbonate; triethylamine; triphenylphosphine; 1-butyl-3-methylimidazolium Tetrafluoroborate; In methanol; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; isopropyl alcohol; acetone; toluene; 7.1: |Noyori Asymmetric Hydrogenation;
DOI:10.1039/c3ob27508f