(Z)-4-benzyl-1-(methoxycarbonyl)-6-<(2,4,5-trimethoxy-3-methylphenyl)methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione

Base Information

Chemical Name:(Z)-4-benzyl-1-(methoxycarbonyl)-6-<(2,4,5-trimethoxy-3-methylphenyl)methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione
CAS No.:113461-81-7
Molecular Formula:C₃₅H₄₀N₂O₁₀
Molecular Weight:648.71
Hs Code.:

Synonyms:(Z)-4-benzyl-1-(methoxycarbonyl)-6-<(2,4,5-trimethoxy-3-methylphenyl)methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione

Suppliers and Price of (Z)-4-benzyl-1-(methoxycarbonyl)-6-<(2,4,5-trimethoxy-3-methylphenyl)methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (Z)-4-benzyl-1-(methoxycarbonyl)-6-<(2,4,5-trimethoxy-3-methylphenyl)methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (Z)-4-benzyl-1-(methoxycarbonyl)-6-<(2,4,5-trimethoxy-3-methylphenyl)methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione

There total 4 articles about (Z)-4-benzyl-1-(methoxycarbonyl)-6-<(2,4,5-trimethoxy-3-methylphenyl)methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 113461-80-6
(Z)-4-benzyl-6-<(2,4,5-trimethoxy-3-methylphenyl)-methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione

: 79-22-1
methyl chloroformate

: 113461-81-7
(Z)-4-benzyl-1-(methoxycarbonyl)-6-<(2,4,5-trimethoxy-3-methylphenyl)methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 25 ℃; for 1h;
DOI:10.1021/jo00253a022

Reference yield:

: 113461-83-9
(Z)-4-benzyl-1-<(benzyloxy)carbonyl>-6-<(2,4,5-trimethoxy-3-methylphenyl)methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione

: 113461-81-7
(Z)-4-benzyl-1-(methoxycarbonyl)-6-<(2,4,5-trimethoxy-3-methylphenyl)methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione

Guidance literature:: Multi-step reaction with 2 steps

1: 57 percent / lithium tri-tert-butylaluminium hydride / tetrahydrofuran / 1 h

2: 92 percent / triethylamine, 4-(dimethylamino)pyridine / CH₂Cl₂ / 1 h / 25 °C

With dmap; lithium tri-tert-butoxyaluminum hydride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00253a022

Reference yield:

: 113479-98-4
(Z)-4-benzyl-1-<(isopropyloxy)carbonyl>-6-<2,4,5-trimethoxy-3-methylphenyl)methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione

: 113461-81-7
(Z)-4-benzyl-1-(methoxycarbonyl)-6-<(2,4,5-trimethoxy-3-methylphenyl)methyl>-3-<(2,4,5-trimethoxy-3-methylphenyl)methylene>-2,5-piperazinedione

Guidance literature:: Multi-step reaction with 2 steps

1: 7 percent / lithium tri-tert-butoxyaluminium hydride / tetrahydrofuran / 1 h

2: 92 percent / triethylamine, 4-(dimethylamino)pyridine / CH₂Cl₂ / 1 h / 25 °C

With dmap; lithium tri(t-butoxy)aluminum hydride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00253a022