adipic acid (4,5-dimethoxy-2-nitrobenzyl) ester (3',5'-dimethoxybenzoin) ester

Base Information

Chemical Name:adipic acid (4,5-dimethoxy-2-nitrobenzyl) ester (3',5'-dimethoxybenzoin) ester
CAS No.:457612-13-4
Molecular Formula:C₃₁H₃₃NO₁₁
Molecular Weight:595.603
Hs Code.:

Synonyms:adipic acid (4,5-dimethoxy-2-nitrobenzyl) ester (3',5'-dimethoxybenzoin) ester

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Chemical Property of adipic acid (4,5-dimethoxy-2-nitrobenzyl) ester (3',5'-dimethoxybenzoin) ester

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Technology Process of adipic acid (4,5-dimethoxy-2-nitrobenzyl) ester (3',5'-dimethoxybenzoin) ester

There total 7 articles about adipic acid (4,5-dimethoxy-2-nitrobenzyl) ester (3',5'-dimethoxybenzoin) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 34904-92-2
2-(3,5-dimethoxyphenyl)-2-hydroxy-1-phenylethan-1-one

: 457612-06-5
adipic acid mono(4,5-dimethoxy-2-nitrobenzyl) ester

: 457612-13-4
adipic acid (4,5-dimethoxy-2-nitrobenzyl) ester (3',5'-dimethoxybenzoin) ester

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In chloroform; at 60 ℃; for 24h;
DOI:10.1021/jo025837m

Reference yield:

: 5425-44-5
2-Phenyl-[1,3]dithiane

: 457612-13-4
adipic acid (4,5-dimethoxy-2-nitrobenzyl) ester (3',5'-dimethoxybenzoin) ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-BuLi / tetrahydrofuran / 0.5 h / 0 °C

1.2: 100 percent / tetrahydrofuran / 1.5 h / 0 - 20 °C

2.1: 56 percent / bis(trifluoroacetoxy)iodobenzene / acetonitrile; H₂O / 1 h / 20 °C

3.1: 76 percent / 4-(N,N-dimethylamino)pyridine; N,N'-dicyclohexylcarbodiimide / CHCl₃ / 24 h / 60 °C

With dmap; n-butyllithium; dicyclohexyl-carbodiimide; bis-[(trifluoroacetoxy)iodo]benzene; In tetrahydrofuran; chloroform; water; acetonitrile;
DOI:10.1021/jo025837m

Reference yield:

: 1016-58-6
6-nitroveratryl alcohol

: 457612-13-4
adipic acid (4,5-dimethoxy-2-nitrobenzyl) ester (3',5'-dimethoxybenzoin) ester

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / 4-(N,N-dimethylamino)pyridine; triethylamine / CHCl₃ / 1 h / 20 °C

2: 58 percent / sodium nitrite; acetic acid; dimethylsulfoxide / 24 h / 45 °C

3: 76 percent / 4-(N,N-dimethylamino)pyridine; N,N'-dicyclohexylcarbodiimide / CHCl₃ / 24 h / 60 °C

With dmap; acetic acid; dimethyl sulfoxide; triethylamine; dicyclohexyl-carbodiimide; sodium nitrite; In chloroform;
DOI:10.1021/jo025837m