2-[(E)-but-2-en-1-yloxy]-6-methyl-4-[(E)-3-(propionyloxy)prop-1-en-1-yl]phenyl pivalate

Base Information

Chemical Name:2-[(E)-but-2-en-1-yloxy]-6-methyl-4-[(E)-3-(propionyloxy)prop-1-en-1-yl]phenyl pivalate
CAS No.:1414861-35-0
Molecular Formula:C₂₂H₃₀O₅
Molecular Weight:374.477
Hs Code.:

Synonyms:2-[(E)-but-2-en-1-yloxy]-6-methyl-4-[(E)-3-(propionyloxy)prop-1-en-1-yl]phenyl pivalate

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Chemical Property of 2-[(E)-but-2-en-1-yloxy]-6-methyl-4-[(E)-3-(propionyloxy)prop-1-en-1-yl]phenyl pivalate

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Technology Process of 2-[(E)-but-2-en-1-yloxy]-6-methyl-4-[(E)-3-(propionyloxy)prop-1-en-1-yl]phenyl pivalate

There total 8 articles about 2-[(E)-but-2-en-1-yloxy]-6-methyl-4-[(E)-3-(propionyloxy)prop-1-en-1-yl]phenyl pivalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 2408-20-0
prop-2-enyl propanoate

: 1414861-34-9
(E)-2-(but-2-enyloxy)-4-iodo-6-methylphenyl pivalate

: 1414861-35-0
2-[(E)-but-2-en-1-yloxy]-6-methyl-4-[(E)-3-(propionyloxy)prop-1-en-1-yl]phenyl pivalate

Guidance literature:: With potassium carbonate; palladium diacetate; In benzene; for 24h; Inert atmosphere; Reflux;
DOI:10.1055/s-0032-1316643

Reference yield:

: 1414861-31-6
5-iodo-2-(methoxymethoxy)-3-methylphenol

: 1414861-35-0
2-[(E)-but-2-en-1-yloxy]-6-methyl-4-[(E)-3-(propionyloxy)prop-1-en-1-yl]phenyl pivalate

Guidance literature:: Multi-step reaction with 4 steps

1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 19 h / 0 - 20 °C / Inert atmosphere

2: acetyl chloride / methanol; dichloromethane / 24 h / 20 °C / Inert atmosphere

3: dmap; triethylamine / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

4: potassium carbonate; palladium diacetate / benzene / 24 h / Inert atmosphere; Reflux

With dmap; di-isopropyl azodicarboxylate; potassium carbonate; palladium diacetate; triethylamine; acetyl chloride; triphenylphosphine; In tetrahydrofuran; methanol; dichloromethane; benzene; 4: |Heck Reaction;
DOI:10.1055/s-0032-1316643

Reference yield:

: 1414861-32-7
(E)-1-(but-2-en-1-yloxy)-5-iodo-2-(methoxymethoxy)-3-methylbenzene

: 1414861-35-0
2-[(E)-but-2-en-1-yloxy]-6-methyl-4-[(E)-3-(propionyloxy)prop-1-en-1-yl]phenyl pivalate

Guidance literature:: Multi-step reaction with 3 steps

1: acetyl chloride / methanol; dichloromethane / 24 h / 20 °C / Inert atmosphere

2: dmap; triethylamine / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

3: potassium carbonate; palladium diacetate / benzene / 24 h / Inert atmosphere; Reflux

With dmap; potassium carbonate; palladium diacetate; triethylamine; acetyl chloride; In methanol; dichloromethane; benzene; 3: |Heck Reaction;
DOI:10.1055/s-0032-1316643