2,2-bis[4-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyloxy)phenyl]propane

Base Information

• Chemical Name: 2,2-bis[4-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyloxy)phenyl]propane
• CAS No.: 871311-19-2
• Molecular Formula: C₄₃H₅₂O₂₀
• Molecular Weight: 888.874
• Mol file: 871311-19-2.mol

Synonyms:2,2-bis[4-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyloxy)phenyl]propane

Chemical Property of 2,2-bis[4-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyloxy)phenyl]propane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2-bis[4-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyloxy)phenyl]propane

There total 1 articles about 2,2-bis[4-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyloxy)phenyl]propane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

BPA (80-05-7) + D-Mannose pentaacetate (83-87-4,604-68-2,604-69-3,2152-77-4,4026-35-1,4163-59-1,4163-60-4,4163-61-5,4163-65-9,4257-94-7,4257-96-9,16299-15-3,19186-39-1,19189-55-0,25878-60-8,25941-03-1,32445-48-0,32445-49-1,32445-53-7,32445-54-8,34685-58-0,34685-59-1,43168-42-9,43168-44-1,43169-22-8,43169-25-1,66966-07-2,70749-17-6,80184-01-6,93221-01-3,93221-02-4,99630-88-3,109215-53-4,115792-70-6,115792-73-9,139894-92-1,139973-25-4,144071-49-8,147648-81-5) → 2,2-bis[4-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyloxy)phenyl]propane (871311-19-2)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at 0 - 20 ℃; for 24h; Inert atmosphere;

DOI:10.1016/j.carres.2011.03.041

Reference yield: 95.0%

2,2-bis[4-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyloxy)phenyl]propane (871311-19-2) → 2,2-bis[4-(α-D-mannopyranosyloxy)phenyl]propane (871311-22-7)

Guidance literature:

2,2-bis[4-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyloxy)phenyl]propane; With sodium methylate; In methanol; at 20 ℃; for 14h; pH=8 - 9; Inert atmosphere;

In methanol;

DOI:10.1016/j.carres.2011.03.041

upstream raw materials:

BPA

D-Mannose pentaacetate

Downstream raw materials:

2,2-bis[4-(α-D-mannopyranosyloxy)phenyl]propane