ethyl 1,3-dihydroxy-9-methyl-7-(4-nitrophenyl)-6-oxo-7,8-dihydro-6H-dibenzo[b,d]pyran-8-carboxylate

Base Information

• Chemical Name: ethyl 1,3-dihydroxy-9-methyl-7-(4-nitrophenyl)-6-oxo-7,8-dihydro-6H-dibenzo[b,d]pyran-8-carboxylate
• CAS No.: 1402930-67-9
• Molecular Formula: C₂₃H₁₉NO₈
• Molecular Weight: 437.406
• Mol file: 1402930-67-9.mol

Synonyms:ethyl 1,3-dihydroxy-9-methyl-7-(4-nitrophenyl)-6-oxo-7,8-dihydro-6H-dibenzo[b,d]pyran-8-carboxylate

Chemical Property of ethyl 1,3-dihydroxy-9-methyl-7-(4-nitrophenyl)-6-oxo-7,8-dihydro-6H-dibenzo[b,d]pyran-8-carboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethyl 1,3-dihydroxy-9-methyl-7-(4-nitrophenyl)-6-oxo-7,8-dihydro-6H-dibenzo[b,d]pyran-8-carboxylate

There total 1 articles about ethyl 1,3-dihydroxy-9-methyl-7-(4-nitrophenyl)-6-oxo-7,8-dihydro-6H-dibenzo[b,d]pyran-8-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

3,5-dihydroxyphenol (108-73-6) + 5-hydroxy-5-methyl-3-(4-nitrophenyl)cyclohexanone-2,4-dicarboxylic acid diethyl ester (93711-15-0) → ethyl 1,3-dihydroxy-9-methyl-7-(4-nitrophenyl)-6-oxo-7,8-dihydro-6H-dibenzo[b,d]pyran-8-carboxylate (1402930-67-9)

Guidance literature:

With methanesulfonic acid; trifluoroacetic acid; for 24h; Reflux;

DOI:10.1055/s-0031-1289810

Reference yield: 48.0%

ethyl 1,3-dihydroxy-9-methyl-7-(4-nitrophenyl)-6-oxo-7,8-dihydro-6H-dibenzo[b,d]pyran-8-carboxylate (1402930-67-9) → ethyl 1,3-dihydroxy-9-methyl-7-(4-nitrophenyl)-6-oxo-6Hdibenzo[b,d]pyran-8-carboxylate (1402930-92-0)

Guidance literature:

With Bromotrichloromethane; 1,8-diazabicyclo[5.4.0]undec-7-ene; In acetonitrile; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1055/s-0031-1289810

upstream raw materials:

3,5-dihydroxyphenol

5-hydroxy-5-methyl-3-(4-nitrophenyl)cyclohexanone-2,4-dicarboxylic acid diethyl ester

Downstream raw materials:

ethyl 1,3-dihydroxy-9-methyl-7-(4-nitrophenyl)-6-oxo-6Hdibenzo[b,d]pyran-8-carboxylate