trans-MeOIr(CO)(PPh₃)2

Base Information

Chemical Name:trans-MeOIr(CO)(PPh₃)2
CAS No.:94070-38-9
Molecular Formula:C₃₈H₃₃IrO₂P₂
Molecular Weight:775.846
Hs Code.:

Synonyms:trans-MeOIr(CO)(PPh₃)2

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Chemical Property of trans-MeOIr(CO)(PPh₃)2

Chemical Property:

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Technology Process of trans-MeOIr(CO)(PPh₃)2

There total 1 articles about trans-MeOIr(CO)(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 617-86-7
triethylsilane

: V(OSi(CH₃)3)3NIr(CO)(P(C₆H₅)3)2

: 94070-38-9
trans-MeOIr(CO)(PPh₃)2

: V(NSi(CH₂CH₃)3)(OSi(CH₃)3)3

Guidance literature:: In benzene-d6; anhydrous and anaerobic conditions; 25°C, 4 d; NMR monitoring;
DOI:10.1016/0277-5387(94)00355-I

Reference yield: 91.0%

: 94070-38-9
trans-MeOIr(CO)(PPh₃)2

: 17000-10-1
HIrCl₂(CO)(PPh₃)2

: 33394-10-4
CH₃C(O)IrCl₂(CO){P(C₆H₅)3}2

: 79-20-9
acetic acid methyl ester

Guidance literature:: With acetyl chloride; In benzene; soln. placed in a pressure tube fitted with a Teflon stopcock, degassed (vac.), acetyl chloride distilled onto the soln., stirred (1 h); solvent removed by vac. distillation; relation of yield to by-product yield depending on the purity of CH3COCl used and on the care of work up;
DOI:10.1021/om00105a034

Reference yield: 90.0%

: 94070-38-9
trans-MeOIr(CO)(PPh₃)2

: 17250-59-8
HIr(PPh₃)2(CO)2

: 107-31-3
Methyl formate

Guidance literature:: With formaldehyd; In tetrahydrofuran; Trans-MeOIr(CO)(PPh3)2 and paraformaldehyde are dissolved in THF and stirred ( 2 days, room temp.).; React. is monitored by IR. Removing of solvent yields yellow solid, chromy. on Florisil (eluant: THF/cyclohexane).;