Technology Process of 3,7,11,15-tetramethyl-13-benzyloxy-14-oxo-2E,6E,10E-hexadecatrienal
There total 10 articles about 3,7,11,15-tetramethyl-13-benzyloxy-14-oxo-2E,6E,10E-hexadecatrienal which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
4-acetoxy-2,2,6,6-tetramethyl-piperidine-1-oxoammonium perchlorate;
In
dichloromethane;
for 0.166667h;
Ambient temperature;
DOI:10.1080/00397919108021291
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 50percent aq. NaOH, TBAB / 5 h / Ambient temperature
2: methanolic K2CO3 / 1 h / Ambient temperature
3: 47 percent / 6percent sodium amalgam, NaHPO4 / methanol / 1 h / 0 °C
4: 95 percent / HgCl2, CaCO3, water / methanol / 1 h / Heating
5: 79 percent / 4-acetoxy-2,2,6,6,-tetramethyl-piperidine-1-oxoammonium perchlorate / CH2Cl2 / 0.5 h / Ambient temperature
With
sodium hydroxide; sodium amalgam; 4-acetoxy-2,2,6,6-tetramethyl-piperidine-1-oxoammonium perchlorate; camphor-10-sulfonic acid; tetrabutylammomium bromide; water; potassium carbonate; calcium carbonate; mercury dichloride;
In
methanol; dichloromethane;
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 95 percent / HgCl2, CaCO3, water / methanol / 1 h / Heating
2: 79 percent / 4-acetoxy-2,2,6,6,-tetramethyl-piperidine-1-oxoammonium perchlorate / CH2Cl2 / 0.5 h / Ambient temperature
With
4-acetoxy-2,2,6,6-tetramethyl-piperidine-1-oxoammonium perchlorate; water; calcium carbonate; mercury dichloride;
In
methanol; dichloromethane;
