(phenyliodophosphido)chlorodicarbonylbis(triphenylphosphine)osmium(II)

Base Information

• Chemical Name: (phenyliodophosphido)chlorodicarbonylbis(triphenylphosphine)osmium(II)
• CAS No.: 94780-59-3
• Molecular Formula: C₄₄H₃₅ClIO₂OsP₃
• Molecular Weight: 1041.24

Synonyms:(phenyliodophosphido)chlorodicarbonylbis(triphenylphosphine)osmium(II)

Chemical Property of (phenyliodophosphido)chlorodicarbonylbis(triphenylphosphine)osmium(II)

Chemical Property:

Purity/Quality:

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Technology Process of (phenyliodophosphido)chlorodicarbonylbis(triphenylphosphine)osmium(II)

There total 3 articles about (phenyliodophosphido)chlorodicarbonylbis(triphenylphosphine)osmium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

C44H36ClO2OsP3 (93366-11-1) → (phenyliodophosphido)chlorodicarbonylbis(triphenylphosphine)osmium(II) (94780-59-3)

Guidance literature:

With I₂; 1,8-diazabicyclo[5.4.0]undec-7-ene; In benzene; byproducts: C9H16N2*HI; N2-atmosphere; addn. of DBU to mixt. of Os-complex and I2 in benzene; stirring for 0.5 h;; cooling in ice; crystn. on addn. of MeOH; filtration; fast washing withMeOH, EtOH, and hexane;;

Reference yield:

[OsCl(PHI(C6H5))(CO)2(P(C6H5)3)2](1+)*ClO4(1-)=[OsCl(PHI(C6H5))(CO)2(P(C6H5)3)2]ClO4 (94780-61-7) → (phenyliodophosphido)chlorodicarbonylbis(triphenylphosphine)osmium(II) (94780-59-3)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In not given; N2-atmosphere; room temp.;

Reference yield:

{Os(PHIC6H5)Cl(CO)2(P(C6H5)3)2}(1+)*I(1-)={Os(PHIC6H5)Cl(CO)2(P(C6H5)3)2}I (94780-58-2) → {Os(PIC6H5)Cl(CO)2(P(C6H5)3)2} (94780-59-3)

Guidance literature:

With 1,8-diazabicyclo{5.4.0}undec-7-ene; In neat (no solvent); recrystn. form benzene/methanol; elem. anal.; detn. by IR;;

DOI:10.1016/0022-328X(84)80514-8

upstream raw materials:

{Os(PHIC₆H₅)Cl(CO)2(P(C₆H₅)3)2}⁽¹⁺⁾*I^(1-)={Os(PHIC₆H₅)Cl(CO)2(P(C₆H₅)3)2}I

[OsCl(PHI(C₆H₅))(CO)2(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[OsCl(PHI(C₆H₅))(CO)2(P(C₆H₅)3)2]ClO₄

C₄₄H₃₆ClO₂OsP₃

Downstream raw materials:

{Os(PCH₃IC₆H₅)Cl(CO)2(P(C₆H₅)3)2}⁽¹⁺⁾*ClO₄^(1-)={Os(PCH₃IC₆H₅)Cl(CO)2(P(C₆H₅)3)2}ClO₄

chloro(phenylmethyliodophosphine)dicarbonylbis(triphenylphosphine)osmium(II) perchlorate - 2-propanol (1/0.5)

(O,O-dimethyl phenylphosphonite)dicarbonylbis(triphenylphosphine)osmium⁽⁰⁾

chloro(O-methyl phenylphosphinite)dicarbonylbis(triphenylphosphine)osmium(II) hexafluoroantimonate

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