5,5-di-tert-butyl-7-(tert-butyl-diphenyl-silanyloxy)-1a-methyl-hexahydro-1,2,4,6-tetraoxa-5-sila-cyclopropa[b]naphthalene

Base Information

Chemical Name:5,5-di-tert-butyl-7-(tert-butyl-diphenyl-silanyloxy)-1a-methyl-hexahydro-1,2,4,6-tetraoxa-5-sila-cyclopropa[b]naphthalene
CAS No.:849833-26-7
Molecular Formula:C₃₁H₄₆O₅Si₂
Molecular Weight:554.874
Hs Code.:

5,5-di-<i>tert</i>-butyl-7-(<i>tert</i>-butyl-diphenyl-silanyloxy)-1a-methyl-hexahydro-1,2,4,6-tetraoxa-5-sila-cyclopropa[<i>b</i>]naphthalene

Synonyms:5,5-di-tert-butyl-7-(tert-butyl-diphenyl-silanyloxy)-1a-methyl-hexahydro-1,2,4,6-tetraoxa-5-sila-cyclopropa[b]naphthalene

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Chemical Property of 5,5-di-tert-butyl-7-(tert-butyl-diphenyl-silanyloxy)-1a-methyl-hexahydro-1,2,4,6-tetraoxa-5-sila-cyclopropa[b]naphthalene

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Technology Process of 5,5-di-tert-butyl-7-(tert-butyl-diphenyl-silanyloxy)-1a-methyl-hexahydro-1,2,4,6-tetraoxa-5-sila-cyclopropa[b]naphthalene

There total 3 articles about 5,5-di-tert-butyl-7-(tert-butyl-diphenyl-silanyloxy)-1a-methyl-hexahydro-1,2,4,6-tetraoxa-5-sila-cyclopropa[b]naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 511256-76-1
(4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-6-methyl-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene

: 849833-26-7
5,5-di-tert-butyl-7-(tert-butyl-diphenyl-silanyloxy)-1a-methyl-hexahydro-1,2,4,6-tetraoxa-5-sila-cyclopropa[b]naphthalene

Guidance literature:: With 3,3-dimethyldioxirane; In dichloromethane; acetone; at -78 ℃; for 0.0833333h;
DOI:10.1021/ol0501469

Reference yield:

: 191593-14-3
4,6-O-di(tert-butyl)silanediyl-D-glucal

: 849833-26-7
5,5-di-tert-butyl-7-(tert-butyl-diphenyl-silanyloxy)-1a-methyl-hexahydro-1,2,4,6-tetraoxa-5-sila-cyclopropa[b]naphthalene

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / imidazole

2: 95 percent / t-BuLi

3: dimethyldioxirane

With 1H-imidazole; tert.-butyl lithium; 3,3-dimethyldioxirane;
DOI:10.1002/chem.200500993

Reference yield:

: 511256-75-0
(4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene

: 849833-26-7
5,5-di-tert-butyl-7-(tert-butyl-diphenyl-silanyloxy)-1a-methyl-hexahydro-1,2,4,6-tetraoxa-5-sila-cyclopropa[b]naphthalene

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / t-BuLi

2: dimethyldioxirane

With tert.-butyl lithium; 3,3-dimethyldioxirane;
DOI:10.1002/chem.200500993