(4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene

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Chemical Name:(4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene
CAS No.:511256-75-0
Molecular Formula:C₃₀H₄₄O₄Si₂
Molecular Weight:524.848
Hs Code.:

Synonyms:(4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene

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Chemical Property of (4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene

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Technology Process of (4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene

There total 1 articles about (4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 191593-14-3
4,6-O-di(tert-butyl)silanediyl-D-glucal

: 511256-75-0
(4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene

Guidance literature:: With 1H-imidazole;
DOI:10.1002/chem.200500993

Reference yield: 95.0%

: 511256-75-0
(4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene

: 74-88-4
methyl iodide

: 511256-76-1
(4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-6-methyl-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene

Guidance literature:: (4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene; With tert.-butyl lithium; In tetrahydrofuran; pentane; at 0 ℃; for 0.5h;

methyl iodide; In tetrahydrofuran; pentane; at -70 - 20 ℃;
DOI:10.1021/ol034100w

Reference yield: 41.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 511256-75-0
(4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene

: 849833-19-8
[2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalen-6-yl]methanol

Guidance literature:: (4aR,8R,8aR)-2,2-di(tert-butyl)-8-(tert-butyldiphenylsilanyloxy)-4,4a,8,8a-tetrahydro-1,3,5-trioxa-2-silanaphthalene; With tert.-butyl lithium; In tetrahydrofuran; pentane; at 0 ℃; for 0.5h;

formaldehyd; In tetrahydrofuran; diethyl ether; pentane; at 0 ℃; for 0.5h;
DOI:10.1021/ol0501469