benzoic acid 1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-cyclohex-1-enyl-prop-2-ynyl ester

Base Information

Chemical Name:benzoic acid 1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-cyclohex-1-enyl-prop-2-ynyl ester
CAS No.:637760-97-5
Molecular Formula:C₂₅H₃₆O₃Si
Molecular Weight:412.645
Hs Code.:

benzoic acid 1-[3-(<i>tert</i>-butyl-dimethyl-silanyloxy)-propyl]-3-cyclohex-1-enyl-prop-2-ynyl ester

Synonyms:benzoic acid 1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-cyclohex-1-enyl-prop-2-ynyl ester

Suppliers and Price of benzoic acid 1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-cyclohex-1-enyl-prop-2-ynyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of benzoic acid 1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-cyclohex-1-enyl-prop-2-ynyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of benzoic acid 1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-cyclohex-1-enyl-prop-2-ynyl ester

There total 2 articles about benzoic acid 1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-cyclohex-1-enyl-prop-2-ynyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 98-88-4
benzoyl chloride

: 637760-94-2
6-(tert-butyl-dimethyl-silanyloxy)-1-cyclohex-1-enyl-hex-1-yn-3-ol

: 637760-97-5
benzoic acid 1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-cyclohex-1-enyl-prop-2-ynyl ester

Guidance literature:: With n-butyllithium; In tetrahydrofuran; at -78 ℃;
DOI:10.1016/j.tetlet.2003.09.091

Reference yield:

: 87184-81-4
4-(tert-butyldimethylsilanyloxy)butanal

: 637760-97-5
benzoic acid 1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-cyclohex-1-enyl-prop-2-ynyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / n-BuLi / tetrahydrofuran / -78 °C

2: 93 percent / n-BuLi / tetrahydrofuran / -78 °C

With n-butyllithium; In tetrahydrofuran;
DOI:10.1016/j.tetlet.2003.09.091

Reference yield:

: 594-19-4
tert.-butyl lithium

: 637760-97-5
benzoic acid 1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-cyclohex-1-enyl-prop-2-ynyl ester

: 637760-99-7
6-cyclohex-1-enyl-7,7-dimethyl-octa-4,5-dien-1-ol

Guidance literature:: tert.-butyl lithium; benzoic acid 1-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-3-cyclohex-1-enyl-prop-2-ynyl ester; In diethyl ether; at -78 ℃;

With tetrabutyl ammonium fluoride; In tetrahydrofuran; diethyl ether;
DOI:10.1016/j.tetlet.2003.09.091