((C₆H₅)3P)2Re(NC₆H₂(CH₃)3)Cl₃

Base Information

• Chemical Name: ((C₆H₅)3P)2Re(NC₆H₂(CH₃)3)Cl₃
• CAS No.: 936729-73-6
• Molecular Formula: C₄₅H₄₁Cl₃NP₂Re
• Molecular Weight: 950.341
• Mol file: 936729-73-6.mol

Synonyms:((C₆H₅)3P)2Re(NC₆H₂(CH₃)3)Cl₃

Chemical Property of ((C₆H₅)3P)2Re(NC₆H₂(CH₃)3)Cl₃

Chemical Property:

Purity/Quality:

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Technology Process of ((C₆H₅)3P)2Re(NC₆H₂(CH₃)3)Cl₃

There total 1 articles about ((C₆H₅)3P)2Re(NC₆H₂(CH₃)3)Cl₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichloromethane-d2 (1665-00-5) + ((C6H5)3P)2Re(NC6H2(CH3)3)Cl2H*1.5C6H6 → ((C6H5)3P)2Re(NC6H2(CH3)3)Cl3 (936729-73-6)

Guidance literature:

In dichloromethane-d2;

DOI:10.1021/ja068872+

Reference yield: 80.0%

triethylsilane (617-86-7) + ((C6H5)3P)2Re(NC6H2(CH3)3)Cl3 (936729-73-6) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → ((C6H5)3P)2Re(NC6H2(CH3)3)Cl2H*1.5C6H6

Guidance literature:

In dichloromethane; byproducts: (C2H5)3SiCl; addn. of Et3SiH to a soln. of ReOCl3(PPh3)2 in CH2Cl2, stirring at room.temp. for 18 h, removal of solvent in vac., addm. opf pentane, filtrati on, washing with pentane, dissolution in benzene, diffusion of pentane to the soln.; elem. anal.;

DOI:10.1021/ja068872+

upstream raw materials:

dichloromethane-d2