(2R)-tert-butyl[4-(methoxymethoxy)-5-methyl-2-(6-methylhept-5-en-2-yl)phenoxy]dimethylsilane

Base Information

Chemical Name:(2R)-tert-butyl[4-(methoxymethoxy)-5-methyl-2-(6-methylhept-5-en-2-yl)phenoxy]dimethylsilane
CAS No.:1260083-83-7
Molecular Formula:C₂₃H₄₀O₃Si
Molecular Weight:392.654
Hs Code.:

Synonyms:(2R)-tert-butyl[4-(methoxymethoxy)-5-methyl-2-(6-methylhept-5-en-2-yl)phenoxy]dimethylsilane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R)-tert-butyl[4-(methoxymethoxy)-5-methyl-2-(6-methylhept-5-en-2-yl)phenoxy]dimethylsilane

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Technology Process of (2R)-tert-butyl[4-(methoxymethoxy)-5-methyl-2-(6-methylhept-5-en-2-yl)phenoxy]dimethylsilane

There total 12 articles about (2R)-tert-butyl[4-(methoxymethoxy)-5-methyl-2-(6-methylhept-5-en-2-yl)phenoxy]dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1260083-82-6
C₁₇H₂₆O₃

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1260083-83-7
(2R)-tert-butyl[4-(methoxymethoxy)-5-methyl-2-(6-methylhept-5-en-2-yl)phenoxy]dimethylsilane

Guidance literature:: With 1H-imidazole; dmap; In dichloromethane; at 20 ℃;
DOI:10.1016/j.tetasy.2010.08.018

Reference yield:

: 3043-64-9
1-phenyl-5-(propane-2-sulfonyl)-pr1H-tetrazole

: 1360594-04-2
C₂₀H₃₄O₄Si

: 1260083-83-7
(2R)-tert-butyl[4-(methoxymethoxy)-5-methyl-2-(6-methylhept-5-en-2-yl)phenoxy]dimethylsilane

Guidance literature:: With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 - 20 ℃; for 0.7h;
DOI:10.1016/j.tetlet.2011.12.115

Reference yield:

: 1313708-40-5
4-(methoxymethoxy)-3-methylphenol

: 1260083-83-7
(2R)-tert-butyl[4-(methoxymethoxy)-5-methyl-2-(6-methylhept-5-en-2-yl)phenoxy]dimethylsilane

Guidance literature:: Multi-step reaction with 6 steps

1: tributylphosphine; 1,1'-azodicarbonyl-dipiperidine / benzene / 0.5 h / 0 - 20 °C

2: trimethylaluminum / hexane / 1 h / 20 °C

3: 1H-imidazole; dmap / dichloromethane / 0.5 h / 20 °C

4: palladium on activated charcoal; hydrogen / tetrahydrofuran / 15 h / 20 °C / 3800.26 Torr

5: oxalyl dichloride; dimethyl sulfoxide; triethylamine / dichloromethane / 0.5 h / -78 - 20 °C

6: lithium hexamethyldisilazane / tetrahydrofuran / 0.7 h / -78 - 20 °C

With 1H-imidazole; dmap; oxalyl dichloride; tributylphosphine; palladium on activated charcoal; hydrogen; trimethylaluminum; dimethyl sulfoxide; triethylamine; lithium hexamethyldisilazane; 1,1'-azodicarbonyl-dipiperidine; In tetrahydrofuran; hexane; dichloromethane; benzene; 1: Mitsunobu coupling / 2: Claisen rearrangement / 5: Swern oxidation / 6: Kocienski-Julia olefination;
DOI:10.1016/j.tetlet.2011.12.115