bis-N,N'-(4-octylphenyl)-bis-N,N'-phenyl-1,4-phenylenediamine

Base Information

• Chemical Name: bis-N,N'-(4-octylphenyl)-bis-N,N'-phenyl-1,4-phenylenediamine
• CAS No.: 1257423-28-1
• Molecular Formula: C₄₆H₅₆N₂
• Molecular Weight: 636.964
• Mol file: 1257423-28-1.mol

Synonyms:bis-N,N'-(4-octylphenyl)-bis-N,N'-phenyl-1,4-phenylenediamine

Chemical Property of bis-N,N'-(4-octylphenyl)-bis-N,N'-phenyl-1,4-phenylenediamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis-N,N'-(4-octylphenyl)-bis-N,N'-phenyl-1,4-phenylenediamine

There total 1 articles about bis-N,N'-(4-octylphenyl)-bis-N,N'-phenyl-1,4-phenylenediamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

1-bromo-4-octylbenzene (51554-93-9) + N,N'-diphenyl-1,4-phenylenediamine (74-31-7,943443-44-5) → bis-N,N'-(4-octylphenyl)-bis-N,N'-phenyl-1,4-phenylenediamine (1257423-28-1)

Guidance literature:

With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; In toluene; at 120 ℃; for 48h; Inert atmosphere;

DOI:10.1039/c0jm01641a

Reference yield: 60.0%

bis-N,N'-(4-octylphenyl)-bis-N,N'-phenyl-1,4-phenylenediamine (1257423-28-1) → bis-N,N'-(4-octylphenyl)-bis-N,N'-(4-bromophenyl)-1,4-phenylenediamine (1257423-29-2)

Guidance literature:

With N-Bromosuccinimide; In N,N-dimethyl-formamide; at 0 - 20 ℃;

DOI:10.1039/c0jm01641a

Reference yield:

bis-N,N'-(4-octylphenyl)-bis-N,N'-phenyl-1,4-phenylenediamine (1257423-28-1) → bis-N,N'-(4-octylphenyl)-bis-N,N'-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)phenyl)-1,4-phenylenediamine (1257423-30-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: N-Bromosuccinimide / N,N-dimethyl-formamide / 0 - 20 °C

2.1: n-butyllithium / tetrahydrofuran / -78 - 20 °C

2.2: -78 - 20 °C

With N-Bromosuccinimide; n-butyllithium; In tetrahydrofuran; N,N-dimethyl-formamide;

DOI:10.1039/c0jm01641a

upstream raw materials:

1-bromo-4-octylbenzene

N,N'-diphenyl-1,4-phenylenediamine

Downstream raw materials:

bis-N,N'-(4-octylphenyl)-bis-N,N'-(4-bromophenyl)-1,4-phenylenediamine

bis-N,N'-(4-octylphenyl)-bis-N,N'-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)phenyl)-1,4-phenylenediamine

C₆₆H₈₄N₂S₂

C₆₆H₈₂Br₂N₂S₂