2,2'-(Hydrazine-1,2-diyl)diethanol

Base Information

• Chemical Name: 2,2'-(Hydrazine-1,2-diyl)diethanol
• CAS No.: 2488-95-1
• Molecular Formula: C4H12 N2 O2
• Molecular Weight: 120.151
• Hs Code.: 2928000090
• European Community (EC) Number: 219-640-9
• NSC Number: 38256
• DSSTox Substance ID: DTXSID90947773
• Nikkaji Number: J191.977F
• Mol file: 2488-95-1.mol

Synonyms:2,2'-(Hydrazine-1,2-diyl)diethanol;2488-95-1;2-[2-(2-hydroxyethyl)hydrazinyl]ethanol;2,2'-Hydrazodiethanol;NSC38256;EINECS 219-640-9;NSC 38256;2,2'-Hydrazobisethanol;beta-Ethoxylethylenediamine;SCHEMBL10325260;4-AMINOBUTYLPHOSPHONICACID;DTXSID90947773;NSC-38256;AKOS006328363;SB84606;2-[2-(2-hydroxyethyl)hydrazino]ethanol;Ethanol, 2,2'-(1,2-hydrazinediyl)bis-;2,2'-(Hydrazine-1,2-diyl)di(ethan-1-ol);2-[N'-(2-Hydroxy-ethyl)-hydrazino]-ethanol;2-[2-(2-hydroxyethyl)hydrazin-1-yl]ethan-1-ol;A877773

Chemical Property of 2,2'-(Hydrazine-1,2-diyl)diethanol

Chemical Property:

• Melting Point: 58-60 °C(Solv: isopropanol (67-63-0))
• Boiling Point: 268.4°Cat760mmHg
• PKA: 14.34±0.10(Predicted)
• Flash Point: 149.4°C
• PSA: 64.52000
• Density: 1.12g/cm³
• LogP: -1.15300
• Storage Temp.: 2-8°C
• XLogP3: -1.8
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 120.089877630
• Heavy Atom Count: 8
• Complexity: 37

Purity/Quality:

99% ^*data from raw suppliers

2,2'-(Hydrazine-1,2-diyl)diethanol 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(CO)NNCCO

Technology Process of 2,2'-(Hydrazine-1,2-diyl)diethanol

There total 7 articles about 2,2'-(Hydrazine-1,2-diyl)diethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1'-biaziridinyl (4388-03-8) → 1,2-bis(2'-hydroxyethyl)-hydrazine (2488-95-1)

Guidance literature:

With hydrogenchloride; potassium iodate; water;

DOI:10.1021/ja01548a035

Reference yield:

3,4-Diaza-2-hexen-1,6-diol (342401-52-9) → 1,2-bis(2'-hydroxyethyl)-hydrazine (2488-95-1)

Guidance literature:

With hydrogen; palladium on activated charcoal;

DOI:10.1021/jo00437a026

Reference yield:

glycolaldehyde dimer (23147-58-2,110822-84-9,110822-85-0,77431-49-3) + 2-hydroxyethylhydrazine (109-84-2) → 1,2-bis(2'-hydroxyethyl)-hydrazine (2488-95-1)

Guidance literature:

Multistep reaction; (i) EtOH, (ii) H₂, Pd-C;

DOI:10.1021/jo00437a026

upstream raw materials:

1,1'-biaziridinyl

glycolaldehyde dimer

2-hydroxyethylhydrazine

3,4-Diaza-2-hexen-1,6-diol

Downstream raw materials:

bis(2-bromoethyl)amine hydrobromide

Refernces

• 1、 Goutelle,Pasquet,Stephan,Bougrine,Delalu. "Kinetic studies of hydrazine and 2-hydroxyethylhydrazine alkylation by 2-chloroethanol: influence of a strong base in the medium". experimental part. p. 382 - 393. Retrieved 2009/11/30.