4-deoxy-1,2-O-(1-methylethylidene)-4-(carboxyamino)-5,6-bis-O-(phenylmethyl)-D-myo-inositol intramol. 3,4-ester

Base Information

Chemical Name:4-deoxy-1,2-O-(1-methylethylidene)-4-(carboxyamino)-5,6-bis-O-(phenylmethyl)-D-myo-inositol intramol. 3,4-ester
CAS No.:582322-13-2
Molecular Formula:C₂₄H₂₇NO₆
Molecular Weight:425.481
Hs Code.:

Synonyms:4-deoxy-1,2-O-(1-methylethylidene)-4-(carboxyamino)-5,6-bis-O-(phenylmethyl)-D-myo-inositol intramol. 3,4-ester

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Chemical Property of 4-deoxy-1,2-O-(1-methylethylidene)-4-(carboxyamino)-5,6-bis-O-(phenylmethyl)-D-myo-inositol intramol. 3,4-ester

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Technology Process of 4-deoxy-1,2-O-(1-methylethylidene)-4-(carboxyamino)-5,6-bis-O-(phenylmethyl)-D-myo-inositol intramol. 3,4-ester

There total 5 articles about 4-deoxy-1,2-O-(1-methylethylidene)-4-(carboxyamino)-5,6-bis-O-(phenylmethyl)-D-myo-inositol intramol. 3,4-ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 582322-12-1
4-deoxy-1,2-O-(1-methylethylidene)-4-[[(1,1-dimethylethoxy)carbonyl]amino]-5,6-bis-O-(phenylmethyl)-D-myo-inositol

: 582322-13-2
4-deoxy-1,2-O-(1-methylethylidene)-4-(carboxyamino)-5,6-bis-O-(phenylmethyl)-D-myo-inositol intramol. 3,4-ester

Guidance literature:: With sodium hydride; In tetrahydrofuran;
DOI:10.1248/cpb.51.100

Reference yield: 48.0%

: 24424-99-5
di-tert-butyl dicarbonate

: (3aR,4R,5R,6S,7R,7aS)-5-Amino-6,7-bis-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-ol

: 582322-13-2
4-deoxy-1,2-O-(1-methylethylidene)-4-(carboxyamino)-5,6-bis-O-(phenylmethyl)-D-myo-inositol intramol. 3,4-ester

: 582322-12-1
4-deoxy-1,2-O-(1-methylethylidene)-4-[[(1,1-dimethylethoxy)carbonyl]amino]-5,6-bis-O-(phenylmethyl)-D-myo-inositol

Guidance literature:: With dmap; In acetonitrile; at 20 ℃; for 20h;
DOI:10.1248/cpb.51.100

Reference yield:

: 4,5-O-(1-methylethylidene)-2,3-bis-O-(phenylmethyl)-D-gluco-hexodialdose 1-[O-(phenylmethyl)oxime]

: 582322-13-2
4-deoxy-1,2-O-(1-methylethylidene)-4-(carboxyamino)-5,6-bis-O-(phenylmethyl)-D-myo-inositol intramol. 3,4-ester

Guidance literature:: Multi-step reaction with 3 steps

1: 59 percent / Bu₃SnH; AIBN / benzene / 1.5 h / Heating

2: LiAlH₄ / tetrahydrofuran / 1 h / Heating

3: 42 percent / DMAP / acetonitrile / 20 h / 20 °C

With dmap; lithium aluminium tetrahydride; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In tetrahydrofuran; acetonitrile; benzene;
DOI:10.1248/cpb.51.100