methyl (1S,4aS,7aS)-7-(hydroxymethyl)-1-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydropyran-2-yl]oxy-1,4a,5,7a-tetrahydrocyclopenta[c]pyran-4-carboxylate

Base Information

Chemical Name:methyl (1S,4aS,7aS)-7-(hydroxymethyl)-1-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydropyran-2-yl]oxy-1,4a,5,7a-tetrahydrocyclopenta[c]pyran-4-carboxylate
CAS No.:24512-63-8
Molecular Formula:C17H24O10
Molecular Weight:388.372
Hs Code.:29389090
European Community (EC) Number:683-175-1
ChEMBL ID:CHEMBL1718933
Metabolomics Workbench ID:68085
Wikipedia:Geniposide
Mol file:24512-63-8.mol

methyl (1S,4aS,7aS)-7-(hydroxymethyl)-1-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydropyran-2-yl]oxy-1,4a,5,7a-tetrahydrocyclopenta[c]pyran-4-carboxylate

Synonyms:geniposide;jasminoidin

Suppliers and Price of methyl (1S,4aS,7aS)-7-(hydroxymethyl)-1-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydropyran-2-yl]oxy-1,4a,5,7a-tetrahydrocyclopenta[c]pyran-4-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
Geniposide
20mg
$ 263.00

Usbiological
Geniposide
5g
$ 345.00

TRC
Geniposide
100mg
$ 110.00

TCI Chemical
Geniposide >95.0%(HPLC)
100mg
$ 82.00

TCI Chemical
Geniposide >95.0%(HPLC)
1g
$ 350.00

Sigma-Aldrich
Geniposide ≥98% (HPLC)
50mg
$ 741.00

Sigma-Aldrich
Geniposide ≥98% (HPLC)
10mg
$ 190.00

JR MediChem
geniposide(NewProduct) 98%
100mg
$ 98.00

DC Chemicals
Geniposide >99%
1 g
$ 1000.00

DC Chemicals
Geniposide >99%
100 mg
$ 250.00

Total 144 raw suppliers

Chemical Property of methyl (1S,4aS,7aS)-7-(hydroxymethyl)-1-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydropyran-2-yl]oxy-1,4a,5,7a-tetrahydrocyclopenta[c]pyran-4-carboxylate

Chemical Property:

Melting Point:161-162 °C
Boiling Point:693.7 °C at 760 mmHg
PKA:12.80±0.70(Predicted)
Flash Point:251.3 °C
PSA：155.14000
Density:1.59 g/cm³
LogP:-2.22910
Storage Temp.:?20°C
Solubility.:H2O: ≥5mg/mL
XLogP3:-2.3
Hydrogen Bond Donor Count:5
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:6
Exact Mass:388.13694696
Heavy Atom Count:27
Complexity:617

Purity/Quality:

99% ^*data from raw suppliers

Geniposide ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Safety Statements: 24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=COC(C2C1CC=C2CO)OC3C(C(C(C(O3)CO)O)O)O
Isomeric SMILES:COC(=O)C1=CO[C@H](C2C1CC=C2CO)O[C@H]3[C@@H]([C@H]([C@@H]([C@H](O3)CO)O)O)O
Uses Geniposide is an iridoid glycoside isolated from the fruit of Gardenia jasminoides Ellis. Geniposide is one of the biologically active ingredients of gardenia fruit. Geniposide is widely used in multi-component injection in the treatment of cerebrovascula

Technology Process of methyl (1S,4aS,7aS)-7-(hydroxymethyl)-1-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydropyran-2-yl]oxy-1,4a,5,7a-tetrahydrocyclopenta[c]pyran-4-carboxylate

There total 8 articles about methyl (1S,4aS,7aS)-7-(hydroxymethyl)-1-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydropyran-2-yl]oxy-1,4a,5,7a-tetrahydrocyclopenta[c]pyran-4-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: