1,4-C₆H₄(COMn(CO)5)2

Base Information

Chemical Name:1,4-C₆H₄(COMn(CO)5)2
CAS No.:17477-08-6
Molecular Formula:C₁₈H₄Mn₂O₁₂
Molecular Weight:522.099
Hs Code.:

1,4-C<sub>6</sub>H<sub>4</sub>(COMn(CO)5)2

Synonyms:1,4-C₆H₄(COMn(CO)5)2

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Chemical Property of 1,4-C₆H₄(COMn(CO)5)2

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Technology Process of 1,4-C₆H₄(COMn(CO)5)2

There total 2 articles about 1,4-C₆H₄(COMn(CO)5)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: sodium amalgam

: 10170-69-1
dimanganese decacarbonyl

: 100-20-9
terephthaloyl chloride

: 17477-08-6
1,4-C₆H₄(COMn(CO)5)2

Guidance literature:: With mercury; In tetrahydrofuran; soln. of Na#Hg, Hg, (Mn(CO)5)2, THF was stirred 1h, excess Na#Hg was drained, filtration through celite (medium porosity frit), addn. of aroyl chloride at ambient temp., warming to room temp., drying in vac., stirring in Et2O; filtration in air, washing with Et2O, distilled H2O, Et2O, hexanes, dried in vac., elem. anal.;

Reference yield: 84.0%

: 17477-07-5
1,4-C₆H₃(Mn(CO)5)2

: 17477-08-6
1,4-C₆H₄(COMn(CO)5)2

Guidance literature:: With carbon monoxide; In tetrahydrofuran; (N2), in an autoclave, stirred at room temp. for 22 h; solvent removed (reduced pressure), washed with ether;
DOI:10.1016/S0277-5387(00)83759-6