Manganese,pentacarbonyliodo-, (OC-6-22)-

Base Information

• Chemical Name: Manganese,pentacarbonyliodo-, (OC-6-22)-
• CAS No.: 14879-42-6
• Molecular Formula: C5I Mn O5
• Molecular Weight: 321.894
• Mol file: 14879-42-6.mol

Synonyms:Manganese,iodopentacarbonyl- (7CI); Manganese, pentacarbonyliodo- (8CI); Iodine manganesepentacarbonyl; Iodomanganese pentacarbonyl; Manganese carbonyl iodide(Mn(CO)5I); Manganese pentacarbonyl iodide; Pentacarbonyliodomanganese

Chemical Property of Manganese,pentacarbonyliodo-, (OC-6-22)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Manganese,pentacarbonyliodo-, (OC-6-22)-

There total 18 articles about Manganese,pentacarbonyliodo-, (OC-6-22)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

bis(triphenylphosphineiminium) pentacarbonylmanganate(1-) (52542-59-3,192520-17-5) + ethyl iodoacetae (623-48-3) → dimanganese decacarbonyl (10170-69-1) + iodo(pentacarbonyl)manganese(I) (14879-42-6) + η1-(CH2COOEt) manganese pentacarbonyl

Guidance literature:

In tetrahydrofuran; (N2 or Ar); 25°C, rapid mixing; determination by NMR;

Reference yield: 68.0%

bis(triphenylphosphineiminium) pentacarbonylmanganate(1-) (52542-59-3,192520-17-5) + ethyl 2-iodopropionate (31253-08-4) → dimanganese decacarbonyl (10170-69-1) + iodo(pentacarbonyl)manganese(I) (14879-42-6) + η1-(CHCH3COOEt) manganese pentacarbonyl

Guidance literature:

In tetrahydrofuran; (N2 or Ar); 25°C, rapid mixing; determination by NMR;

Reference yield: 35.0%

sodium pentacarbonyl manganate (13859-41-1) + ethyl 2-iodopropionate (31253-08-4) → dimanganese decacarbonyl (10170-69-1) + iodo(pentacarbonyl)manganese(I) (14879-42-6) + η1-(CHCH3COOEt) manganese pentacarbonyl

Guidance literature:

In tetrahydrofuran; (N2 or Ar); rapid mixing at room temp.;

upstream raw materials:

bis(triphenylphosphineiminium) pentacarbonylmanganate^(1-)

ethyl 2-iodo-2-methylpropanoate

Iodine monochloride

Mn(CO)5(Sn(CH₃)3)

Downstream raw materials:

dimanganese decacarbonyl

bis(η6-1,3,5-trimethylbenzene)vanadium(I) iodide

Mn₂(CO)8I₂

Mn(CO)3(P(O(C₆H₅))3)2I