RuHClC₆(CH₃)6P(C₆H₅)3

Base Information

• Chemical Name: RuHClC₆(CH₃)6P(C₆H₅)3
• CAS No.: 75182-14-8
• Molecular Formula: C₃₀H₃₄ClPRu
• Molecular Weight: 562.097
• Mol file: 75182-14-8.mol

Synonyms:RuHClC₆(CH₃)6P(C₆H₅)3

Chemical Property of RuHClC₆(CH₃)6P(C₆H₅)3

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of RuHClC₆(CH₃)6P(C₆H₅)3

There total 4 articles about RuHClC₆(CH₃)6P(C₆H₅)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

[RuCl2(hexamethylbenzene)]2 + triphenylphosphine (603-35-0) → RuHClC6(CH3)6P(C6H5)3 (75182-14-8)

Guidance literature:

With sodium carbonate; In isopropyl alcohol; under N2 or Ar; suspending of 0.92 mmol (RuCl2(η-C6(CH3)6))2, 5.18 mmol Na2CO3 and 5.03 mmol P(C6H5)3 in propan-2-ol; heating to reflux for15 h; cooling; evapn. to dryness under reduced pressure;; extraction with toluene; filtration; evapn. under reduced pressure; addn. of n-hexane; elem. anal.;;

DOI:10.1016/0022-328X(84)80466-0

Reference yield: 35.0%

(η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II) (82498-46-2) → RuHClC6(CH3)6P(C6H5)3 (75182-14-8)

Guidance literature:

With sodium carbonate; In water; isopropyl alcohol; under N2 or Ar: heating of RuCl2(η-C6(CH3)6)(P(C6H5)3) with Na2CO3 in aq. propan-2-ol; pptn.;;

DOI:10.1016/0022-328X(84)80466-0

Reference yield:

dichloro(μ-chloro)(μ-hydrido)bis(η-hexamethylbenzene)diruthenium(II) (90720-53-9) → (η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II) (82498-46-2) + RuHClC6(CH3)6P(C6H5)3 (75182-14-8)

Guidance literature:

With triphenylphosphine; In benzene; refluxing benzene, 2 h;; filtered, evapd. to dryness;;

upstream raw materials:

dichloro(μ-chloro)(μ-hydrido)bis(η-hexamethylbenzene)diruthenium(II)

triphenylphosphine

(η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II)

Downstream raw materials:

RuH(o-C6H4P(C6H5)2)(η-C6(CH3)6)