(η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II)

Base Information

• Chemical Name: (η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II)
• CAS No.: 82498-46-2
• Molecular Formula: C₃₀H₃₃Cl₂PRu
• Molecular Weight: 596.542
• Mol file: 82498-46-2.mol

Synonyms:(η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II)

Chemical Property of (η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of (η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II)

There total 9 articles about (η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

[RuCl2(hexamethylbenzene)]2 + triphenylphosphine (603-35-0) → (η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II) (82498-46-2)

Guidance literature:

In isopropyl alcohol; under N2 or Ar; suspending of 0.45 mmol (RuCl2(η-C6(CH3)6))2 and 1 mmol P(C6H5)3 in propan-2-ol; heating to reflux for 2 h; evapn. to dryness under reduced pressure;; recrystn. from CHCl3/n-hexane; elem. anal.;;

DOI:10.1016/0022-328X(84)80466-0

Reference yield: 80.0%

[RuCl2(hexamethylbenzene)]2 → (η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II) (82498-46-2)

Guidance literature:

With triphenylphosphine; In chloroform; a soln. of Ru dimer in CHCl3 was treated under inert atmosphere with anexcess of PPh3, mixt. was refluxed for 2 h; soln. was filtered, concd., hexane was added, ppt. was collected, washed with hexane for 3 times, dried, recrystd. from CH2Cl2-Et2O; elem. anal.;

DOI:10.1016/S0022-328X(00)84330-2

Reference yield: 75.0%

[Ru(η6-C6Me6)Cl2]2(μ-1,4-dicyano-trans-2-butene) + triphenylphosphine (603-35-0) → (η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II) (82498-46-2)

Guidance literature:

In methanol; refluxing (30 min), pptn., cooling (room temp.); filtration, washing (methanol, diethyl ether), drying (vac.); elem. anal.;

upstream raw materials:

Ru(C₆(CH₃)6)Cl₂(C₄H₈(CN₂)2)

triphenylphosphine

[Ru(C₆(CH₃)6)Cl₂]2(C₄H₈(CN₂)2)

[(η6-hexamethylbenzene)RuCl2(4-cyanopyridine)]

Downstream raw materials:

(η6-C6Me6)Ru(OCOCF3)2(PPh3)

[Ru(η6-C6Me6)(PPh3)Cl((CN)2C6H4)]PF6

(η(6)-C6Me6)RuMePh(PPh3)

[Ru{CH(CN)C(O)N(CO₂Et)}(PPh₃)(η⁶-C₆Me₆)]