1-tert-butyldimetylsiloxymethyl-4-phenylmethyl-1,4-epoxy-1,4-dihydronaphthalene

Base Information

• Chemical Name: 1-tert-butyldimetylsiloxymethyl-4-phenylmethyl-1,4-epoxy-1,4-dihydronaphthalene
• CAS No.: 1450917-57-3
• Molecular Formula: C₂₈H₃₀O₂Si
• Molecular Weight: 426.631
• Mol file: 1450917-57-3.mol

Synonyms:1-tert-butyldimetylsiloxymethyl-4-phenylmethyl-1,4-epoxy-1,4-dihydronaphthalene

Chemical Property of 1-tert-butyldimetylsiloxymethyl-4-phenylmethyl-1,4-epoxy-1,4-dihydronaphthalene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1-tert-butyldimetylsiloxymethyl-4-phenylmethyl-1,4-epoxy-1,4-dihydronaphthalene

There total 1 articles about 1-tert-butyldimetylsiloxymethyl-4-phenylmethyl-1,4-epoxy-1,4-dihydronaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-tert-butyldimetylsiloxymethyl-4-methylfuran (1450917-75-5) + anthranilic acid (118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4) → 1-tert-butyldimetylsiloxymethyl-4-phenylmethyl-1,4-epoxy-1,4-dihydronaphthalene (1450917-57-3)

Guidance literature:

With isopentyl nitrite; In tetrahydrofuran; at 95 ℃; Inert atmosphere;

DOI:10.1002/anie.201207315

Reference yield: 86.0%

1-tert-butyldimetylsiloxymethyl-4-phenylmethyl-1,4-epoxy-1,4-dihydronaphthalene (1450917-57-3) + (E)-trimethyl(3-phenylallyl)silane (40595-34-4) → trans-6-methyl-3-phenyl-2-trimethylsilylmethyl-3,4-dihydro-2H-naphtho[1,2-b]pyran

Guidance literature:

With iron(III) chloride; chloro-trimethyl-silane; In dichloromethane; at -40 - 20 ℃; for 1.5h; Reagent/catalyst; Time; Inert atmosphere;

DOI:10.1002/anie.201207315

Reference yield: 25.0%

1-tert-butyldimetylsiloxymethyl-4-phenylmethyl-1,4-epoxy-1,4-dihydronaphthalene (1450917-57-3) + cinnamyltrimethylsilane (19752-23-9) → trans-6-methyl-3-phenyl-2-trimethylsilylmethyl-3,4-dihydro-2H-naphtho[1,2-b]pyran + C24H28OSi

Guidance literature:

With iron(III) chloride; chloro-trimethyl-silane; In dichloromethane; at -40 - 20 ℃; for 1.5h; Reagent/catalyst; Time; Inert atmosphere;

DOI:10.1002/anie.201207315

upstream raw materials:

1-tert-butyldimetylsiloxymethyl-4-methylfuran

anthranilic acid