Cinnamyltrimethylsilane

Base Information

• Chemical Name: Cinnamyltrimethylsilane
• CAS No.: 19752-23-9
• Molecular Formula: C12H18Si
• Molecular Weight: 190.36
• Mol file: 19752-23-9.mol

Synonyms:trimethyl(3-phenylallyl)silane;cinnamyltrimethylsilane;(E/Z)-1-(Trimethylsilyl)-3-phenylprop-2-ene;cinnamylthimethylsilane;1-phenyl-3-(trimethylsilyl)-1-propene;3-phenylallyltrimethylsilane;1-Phenyl-3-(trimethylsilyl)-propen;

Chemical Property of Cinnamyltrimethylsilane

Chemical Property:

• PSA: 0.00000
• LogP: 4.03800
• Storage Temp.: 2-8°C

Purity/Quality:

98% ^*data from raw suppliers

Cinnamyltrimethylsilane 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cinnamyltrimethylsilane

There total 41 articles about Cinnamyltrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

chloro-trimethyl-silane (75-77-4) + cinnamyl chloride (2687-12-9) → cinnamyltrimethylsilane (19752-23-9)

Guidance literature:

With iodine; magnesium; In tetrahydrofuran; at -78 - 25 ℃; for 2.5h;

DOI:10.1021/acs.orglett.0c02736

Reference yield: 85.0%

(2-Phenyl-aziridin-1-yl)-[1-phenyl-3-trimethylsilanyl-prop-(Z)-ylidene]-amine (144487-92-3) → cinnamyltrimethylsilane (19752-23-9)

Guidance literature:

With dirhodium tetraacetate; In toluene; at 145 ℃; for 2.5h;

DOI:10.1039/c39920001184

Reference yield: 83.0%

C14H21ClO2Si → cinnamyltrimethylsilane (19752-23-9)

Guidance literature:

With samarium diiodide; In tetrahydrofuran; for 8h; Heating;

DOI:10.1055/s-2006-958436

upstream raw materials:

(2-trimethylsilylethylidene)triphenylphosphorane

benzaldehyde

trans-3-phenylprop-2-enyl chloride

chloro-trimethyl-silane

Downstream raw materials:

3,4,4-triphenyl-1-butene

3,4-diphenyl-4-methyl-1-pentene

1-phenylpropene

2-phenylethylstyrene

Refernces

• 1、 Addanki, Rupa Bai,Halder, Suvendu,Kancharla, Pavan K.. "TfO-···H-O-H Interaction-Assisted Generation of a Silicon Cation from Allylsilanes: Access to Phenylallyl Ferrier Glycosides from Glycals". supporting information. . Retrieved 2022/02/23.
• 2、 Estopi?á-Durán, Susana,McLean, Euan B.,Donnelly, Liam J.,Hockin, Bryony M.,Taylor, James E.. "Arylboronic Acid Catalyzed C-Alkylation and Allylation Reactions Using Benzylic Alcohols". supporting information. p. 7547 - 7551. Retrieved 2020/10/09.