(S)-methyl N-(benzyloxycarbonyl)[(but-3-enyl)diphenylsilanyloxy]isoserinate

Base Information

Chemical Name:(S)-methyl N-(benzyloxycarbonyl)[(but-3-enyl)diphenylsilanyloxy]isoserinate
CAS No.:866006-97-5
Molecular Formula:C₂₈H₃₁NO₅Si
Molecular Weight:489.643
Hs Code.:

Synonyms:(S)-methyl N-(benzyloxycarbonyl)[(but-3-enyl)diphenylsilanyloxy]isoserinate

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Chemical Property of (S)-methyl N-(benzyloxycarbonyl)[(but-3-enyl)diphenylsilanyloxy]isoserinate

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Technology Process of (S)-methyl N-(benzyloxycarbonyl)[(but-3-enyl)diphenylsilanyloxy]isoserinate

There total 1 articles about (S)-methyl N-(benzyloxycarbonyl)[(but-3-enyl)diphenylsilanyloxy]isoserinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 89561-32-0
(but-3-enyl)diphenylsilane

: 135582-87-5
(S)-methyl 3-(benzyloxycarbonylamino)-2-hydroxypropanoate

: 866006-97-5
(S)-methyl N-(benzyloxycarbonyl)[(but-3-enyl)diphenylsilanyloxy]isoserinate

Guidance literature:: With tris(pentafluorophenyl)borate; In dichloromethane; for 16h; Heating;
DOI:10.1021/jo050644v

Reference yield: 100.0%

: 866006-97-5
(S)-methyl N-(benzyloxycarbonyl)[(but-3-enyl)diphenylsilanyloxy]isoserinate

: 866006-98-6
(S)-methyl N-(benzyloxycarbonyl)[(E-but-2-enyl)diphenylsilanyloxy]isoserinate

Guidance literature:: With (1,5-cyclooctadiene)bis(methyldiphenylphosphine) iridium hexafluorophosphate; In dichloromethane; at 0 ℃; for 0.583333h;
DOI:10.1021/jo050644v

Reference yield:

: 866006-97-5
(S)-methyl N-(benzyloxycarbonyl)[(but-3-enyl)diphenylsilanyloxy]isoserinate

: [(4S,5S)-5-((R)-1-Methyl-allyl)-2,2-diphenyl-[1,3,2]dioxasilolan-4-ylmethyl]-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / [(COD)Ir(PPh₂Me)2]⁽¹⁺⁾PF₆^(1-) / CH₂Cl₂ / 0.58 h / 0 °C

2: 50 percent / DIBAL / CH₂Cl₂ / 2 h / -78 °C

3: toluene / 17 h / 130 °C

With (1,5-cyclooctadiene)bis(methyldiphenylphosphine) iridium hexafluorophosphate; diisobutylaluminium hydride; In dichloromethane; toluene;
DOI:10.1021/jo050644v