(Z)-2-tert-Butoxycarbonylamino-3-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-acrylic acid benzyl ester

Base Information

Chemical Name:(Z)-2-tert-Butoxycarbonylamino-3-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-acrylic acid benzyl ester
CAS No.:121056-87-9
Molecular Formula:C₃₉H₆₅NO₇Si₃
Molecular Weight:744.204
Hs Code.:

Synonyms:(Z)-2-tert-Butoxycarbonylamino-3-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-acrylic acid benzyl ester

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Chemical Property of (Z)-2-tert-Butoxycarbonylamino-3-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-acrylic acid benzyl ester

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Technology Process of (Z)-2-tert-Butoxycarbonylamino-3-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-acrylic acid benzyl ester

There total 8 articles about (Z)-2-tert-Butoxycarbonylamino-3-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-acrylic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 24424-99-5
di-tert-butyl dicarbonate

: 121056-87-9
(Z)-2-tert-Butoxycarbonylamino-3-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-acrylic acid benzyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: CH₂Cl₂

2: 83 percent / 1 N KOH / 0.25 h

3: 75 percent / DBU / acetonitrile / 2 h / Ambient temperature

4: 1) NaH / 1.) THF, room temp., 20 min, 2.) 5 h

With potassium hydroxide; sodium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; acetonitrile;
DOI:10.1021/ja00198a040

Reference yield:

: 99-24-1
methyl galloate

: 121056-87-9
(Z)-2-tert-Butoxycarbonylamino-3-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-acrylic acid benzyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 93 percent / imidazole / dimethylformamide / 20 h

2: 79 percent / LiAlH₄ / tetrahydrofuran / 3 h / Heating

3: 75 percent / pyridinium chlorochromate / CH₂Cl₂ / 4 h / Ambient temperature

4: 1) NaH / 1.) THF, room temp., 20 min, 2.) 5 h

With 1H-imidazole; lithium aluminium tetrahydride; sodium hydride; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00198a040

Reference yield:

: 121056-96-0
(±)-2-((tert-butoxycarbonyl)amino)-2-(dimethoxyphosphoryl)acetic acid

: 121056-87-9
(Z)-2-tert-Butoxycarbonylamino-3-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-acrylic acid benzyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 75 percent / DBU / acetonitrile / 2 h / Ambient temperature

2: 1) NaH / 1.) THF, room temp., 20 min, 2.) 5 h

With sodium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In acetonitrile;
DOI:10.1021/ja00198a040