1-Methoxy-3-((E)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-iodo-oct-1-enyl)-benzene

Base Information

• Chemical Name: 1-Methoxy-3-((E)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-iodo-oct-1-enyl)-benzene
• CAS No.: 790703-04-7
• Molecular Formula: C₁₅H₈F₁₃IO
• Molecular Weight: 578.112
• Mol file: 790703-04-7.mol

Synonyms:1-Methoxy-3-((E)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-iodo-oct-1-enyl)-benzene

Chemical Property of 1-Methoxy-3-((E)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-iodo-oct-1-enyl)-benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-Methoxy-3-((E)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-iodo-oct-1-enyl)-benzene

There total 1 articles about 1-Methoxy-3-((E)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-iodo-oct-1-enyl)-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

n-perfluorohexyl iodide (355-43-1) + 1-ethynyl-3-methoxybenzene (768-70-7) → 1-Methoxy-3-((E)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-iodo-oct-1-enyl)-benzene (790703-04-7)

Guidance literature:

With di-tert-butyl peroxide; at 110 - 120 ℃; for 24h;

DOI:10.1016/j.tetlet.2004.08.080

Reference yield: 56.0%

dibenzylamine (103-49-1) + 1-Methoxy-3-((E)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-iodo-oct-1-enyl)-benzene (790703-04-7) → Dibenzyl-{2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-1-[1-(3-methoxy-phenyl)-meth-(Z)-ylidene]-heptyl}-amine (790703-53-6)

Guidance literature:

dibenzylamine; With n-butyllithium; In tetrahydrofuran; toluene; at 20 ℃;

1-Methoxy-3-((E)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-iodo-oct-1-enyl)-benzene; In tetrahydrofuran; toluene; at 70 ℃; for 12h; Further stages.;

DOI:10.1016/j.tetlet.2004.08.080

Reference yield: 55.0%

morpholine (110-91-8,99108-56-2) + 1-Methoxy-3-((E)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-iodo-oct-1-enyl)-benzene (790703-04-7) → 4-{2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-[1-(3-methoxy-phenyl)-meth-(Z)-ylidene]-heptyl}-morpholine (790703-48-9)

Guidance literature:

morpholine; With n-butyllithium; In tetrahydrofuran; toluene; at 20 ℃;

1-Methoxy-3-((E)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-iodo-oct-1-enyl)-benzene; In tetrahydrofuran; toluene; at 70 ℃; for 12h; Further stages.;

DOI:10.1016/j.tetlet.2004.08.080

upstream raw materials:

n-perfluorohexyl iodide

1-ethynyl-3-methoxybenzene

Downstream raw materials:

4-{2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-[1-(3-methoxy-phenyl)-meth-(Z)-ylidene]-heptyl}-morpholine

Dibenzyl-{2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-1-[1-(3-methoxy-phenyl)-meth-(Z)-ylidene]-heptyl}-amine