1,3,4-tri-O-benzoyl-6-deoxy-β-D-arabino-hexopyranos-2-ulose monohydrate

Base Information

• Chemical Name: 1,3,4-tri-O-benzoyl-6-deoxy-β-D-arabino-hexopyranos-2-ulose monohydrate
• CAS No.: 88773-24-4
• Molecular Formula: C₂₇H₂₄O₉
• Molecular Weight: 492.482
• Mol file: 88773-24-4.mol

Synonyms:1,3,4-tri-O-benzoyl-6-deoxy-β-D-arabino-hexopyranos-2-ulose monohydrate

Chemical Property of 1,3,4-tri-O-benzoyl-6-deoxy-β-D-arabino-hexopyranos-2-ulose monohydrate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3,4-tri-O-benzoyl-6-deoxy-β-D-arabino-hexopyranos-2-ulose monohydrate

There total 2 articles about 1,3,4-tri-O-benzoyl-6-deoxy-β-D-arabino-hexopyranos-2-ulose monohydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

1,5-anhydro-2,3,4-tri-O-benzoyl-6-deoxy-D-arabino-hex-1-enitol (52080-34-9) → 2,3,4-tri-O-benzoyl-2-chloro-6-deoxy-α-D-mannopyranosyl chloride (52147-64-5) + 1,3,4-tri-O-benzoyl-6-deoxy-β-D-arabino-hexopyranos-2-ulose monohydrate (88773-24-4) + C27H24O9 (88773-24-4)

Guidance literature:

With water; chlorine; In toluene; 1) -20 deg C, 10 min, 2) RT, 20 min;

Reference yield: 10.0%

1,5-anhydro-2,3,4-tri-O-benzoyl-6-deoxy-D-arabino-hex-1-enitol (52080-34-9) → 2,3,4-tri-O-benzoyl-2-chloro-6-deoxy-α-D-mannopyranosyl chloride (52147-64-5) + 1,3,4-tri-O-benzoyl-6-deoxy-β-D-arabino-hexopyranos-2-ulose monohydrate (88773-24-4) + C27H24O9 (88773-24-4)

Guidance literature:

With water; chlorine; In toluene; 1) -20 deg C, 10 min, 2) RT, 20 min;

Reference yield: 79.0%

1,3,4-tri-O-benzoyl-6-deoxy-β-D-arabino-hexopyranos-2-ulose monohydrate (88773-24-4) → (2S,6R)-2,4-bis(benzoyloxy)-6-methyl-2H-pyran-3(6H)-one (88824-89-9)

Guidance literature:

With water; sodium hydrogencarbonate; In benzene; for 1.5h; Heating;

upstream raw materials:

1,5-anhydro-2,3,4-tri-O-benzoyl-6-deoxy-D-arabino-hex-1-enitol

Downstream raw materials:

(2S,6R)-2,4-bis(benzoyloxy)-6-methyl-2H-pyran-3(6H)-one

5-benzoyloxy-2-methyl-4H-pyran-4-one

(2R)-5-benzoyloxy-2-methyl-2H-pyran-4(3H)-one

(2R,6R)-2-chloro-4-benzoyloxy-6-methyl-2H-pyran-3-(6H)-one